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597910

Sigma-Aldrich

(4-氯苯基)三乙氧基硅烷

97%

同義詞:

氯代苯基三乙氧基硅烷

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About This Item

線性公式:
ClC6H4Si(OC2H5)3
CAS號碼:
分子量::
274.82
EC號碼:
MDL號碼:
分類程式碼代碼:
12352103
PubChem物質ID:
NACRES:
NA.22

品質等級

化驗

97%

折射率

n20/D 1.474 (lit.)

bp

82-84 °C/0.07 mmHg (lit.)

密度

1.069 g/mL at 25 °C (lit.)

SMILES 字串

CCO[Si](OCC)(OCC)c1ccc(Cl)cc1

InChI

1S/C12H19ClO3Si/c1-4-14-17(15-5-2,16-6-3)12-9-7-11(13)8-10-12/h7-10H,4-6H2,1-3H3

InChI 密鑰

AFILDYMJSTXBAR-UHFFFAOYSA-N

應用

(4-Chlorophenyl)triethoxysilane can be used:
  • To facilitate the connection between dipolar mixed monolayers and zinc oxide in photovoltaic devices.
  • As a substrate in the Ni-catalyzed decarboxylative coupling with alkynyl carboxylic acids to yield substituted diarylalkynes.
  • As a substrate in the Hiyama cross-coupling reactions with 3-iodoazetidines to yield substituted 3-arylazetidines.
  • As an intermediate in the synthesis of tripod-shaped oligo(p-phenylene)s, which are used in the surface immobilization of gold and CdS quantum dots for sensor applications.

儲存類別代碼

10 - Combustible liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

>230.0 °F - closed cup

閃點(°C)

> 110 °C - closed cup

個人防護裝備

Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)


分析證明 (COA)

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Tuning zinc oxide/organic energy level alignment using mixed triethoxysilane monolayers
Brenner TM, et al.
Journal of Material Chemistry C, 1(37), 5935-5943 (2013)
Synthesis of azobenzene substituted tripod-shaped bi (p-phenylene) s. Adsorption on gold and CdS quantum-dots surfaces
Hierrezuelo J, et al.
Tetrahedron, 69(16), 3465-3474 (2013)
Palladium-Catalyzed Hiyama Cross-Couplings of Arylsilanes with 3-Iodoazetidine: Synthesis of 3-Arylazetidines
Liu Z, et al.
The Journal of Organic Chemistry, 84(19), 12358-12365 (2019)
Nickel-catalyzed Hiyama-type decarboxylative coupling of propiolic acids and organosilanes
Edwin Raja GC, et al.
The Journal of Organic Chemistry, 81(12), 5244-5249 (2016)
Denmark, S. E.; Ober, M. H.
Aldrichimica Acta, 36, 75-75 (2003)

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