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About This Item
線性公式:
CH3C6H4BF3K
CAS號碼:
分子量：:
198.03
MDL號碼:
分類程式碼代碼:
12352103
PubChem物質ID:
NACRES:
NA.22
推薦產品
形狀
solid
SMILES 字串
[K+].Cc1ccc(cc1)[B-](F)(F)F
InChI
1S/C7H7BF3.K/c1-6-2-4-7(5-3-6)8(9,10)11;/h2-5H,1H3;/q-1;+1
InChI 密鑰
KRWDYXJWQBTBAH-UHFFFAOYSA-N
應用
Potassium p-tolyltrifluoroborate can be used:
- As a precursor/starting material for the synthesis of biaryl compounds by reacting with various aryl halides using Pd/C catalyst.
- As a reagent in the carbonylative arylation of vinyl ketones via 1,4-addition.
- As a substrate in the synthesis of primary arylamines by reacting with hydroxylamine-O-sulfonic acid under metal-free conditions.
訊號詞
Warning
危險聲明
危險分類
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
標靶器官
Respiratory system
儲存類別代碼
11 - Combustible Solids
水污染物質分類（WGK）
WGK 3
閃點（°F）
Not applicable
閃點（°C）
Not applicable
個人防護裝備
dust mask type N95 (US), Eyeshields, Gloves
分析證明 (COA)
輸入產品批次/批號來搜索 分析證明 (COA)。在產品’s標籤上找到批次和批號，寫有 ‘Lot’或‘Batch’.。
Palladium on carbon-catalyzed cross-coupling of aryl halides with potassium p-tolyltrifluoroborate in air
LeBlond CR, et al.
Synthetic Communications, 39(4), 636-640 (2009)
Carbonylative 1, 4-addition of potassium aryltrifluoroborates to vinyl ketones
Sauthier M, et al.
New. J. Chem., 33(5), 969-971 (2009)
Oxygen-promoted Pd/C-catalyzed Suzuki-Miyaura reaction of potassium aryltrifluoroborates
Liu C, et al.
Chinese Chemical Letters = Zhongguo Hua Xue Kuai Bao, 27(5), 631-634 (2016)
Sonication and Microwave-Assisted Primary Amination of Potassium Aryltrifluoroborates and Phenylboronic Acids under Metal-Free Conditions
Kuik D, et al.
Synthesis, 49(11), 2555-2561 (2017)
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