547794

三[N,N-双(三甲基硅烷)胺]钕(III)

97%

• 同義詞: 1,1,1-Trimethyl-N-(trimethylsilyl)silanamine neodymium(III) salt
• 線性公式: Nd(N(Si(CH₃)₃)₂)₃
• CAS號碼: 148274-47-9
• 分子量：: 625.39
• MDL號碼: MFCD03427089
• 分類程式碼代碼: 12352300
• PubChem物質ID: 24878980

屬性

• 化驗: 97%
• 形狀: solid
• 反應適用性: reagent type: catalyst; core: neodymium
• mp: 156-159 °C (lit.)
• SMILES 字串: C[Si](C)(C)N([Nd](N([Si](C)(C)C)[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)[Si](C)(C)C
• InChI: 1S/3C6H18NSi2.Nd/c3*1-8(2,3)7-9(4,5)6;/h3*1-6H3;/q3*-1;+3
• InChI 密鑰: LWKIKGQVWYVALF-UHFFFAOYSA-N

描述

應用

Reagent for synthesis of:

• Imidophosphinate complexes of lanthanides
• Neodymium methoxides containing thienyl substituents
• Phenylene-bridged binuclear organolanthanide complexes
• Near-infrared photoluminescent neodymium(III) complexes

Reagent for:

• Rare-earth metal carboxylate-based catalysts
• Regioselective C-H activation

安全資訊

• 象形圖: GHS02,GHS05
• 訊號詞: Danger
• 危險聲明: H228,H261,H314
• 防範說明: P210 - P231 + P232 - P260 - P280 - P303 + P361 + P353 - P305 + P351 + P338
• 危險分類: Flam. Sol. 1 - Skin Corr. 1B - Water-react 2
• 安全危害: EUH014
• 儲存類別代碼: 4.3 - Hazardous materials which set free flammable gases upon contact with water
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: 36.0 °F - closed cup
• 閃點（°C）: 2.2 °C - closed cup
• 個人防護裝備: Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges