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About This Item
經驗公式（希爾表示法）:
C21H26
CAS號碼:
分子量：:
278.43
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22
推薦產品
化驗
98%
mp
121-124 °C (lit.)
SMILES 字串
CC(C)(C)c1ccc-2c(Cc3cc(ccc-23)C(C)(C)C)c1
InChI
1S/C21H26/c1-20(2,3)16-7-9-18-14(12-16)11-15-13-17(21(4,5)6)8-10-19(15)18/h7-10,12-13H,11H2,1-6H3
InChI 密鑰
DFZYPLLGAQIQTD-UHFFFAOYSA-N
一般說明
2,7-Di-tert-butylfluorene can be synthesized by reacting fluorene, CS2 and FeCl3 and 2-chloro-2-methylpropane. It can also be obtained by reacting fluorene with tert-butyl chloride in the presence of FeCl3.
應用
2,7-Di-tert-butylfluorene may be used in the preparation of:
- 2,7-di-tert-butyl-9-fluorenylmethanol
- 2,7-di-tert-butyl-9-[ [(p-chlorophenyl)amino]methylene]-fluorene
- dihydrocyclohepta[def]fluorene
- new group 4 metal complexes containing aminofluorenyl ligands
儲存類別代碼
11 - Combustible Solids
水污染物質分類（WGK）
WGK 3
閃點（°F）
Not applicable
閃點（°C）
Not applicable
個人防護裝備
Eyeshields, Gloves, type N95 (US)
Investigation of the reaction between amino acids or amino acid esters and 9-formylfluorene and its equivalents. Possible utility of the derived enamines as amino group protectants.
Carpino LA, et al.
The Journal of Organic Chemistry, 54(18), 4302-4313 (1989)
Synthesis and Properties of Kinetically Stabilized Cyclohepta [def] fluorene Derivatives.
Grieser, UD and Hafner K.
Chemische Berichte, 127(11), 2307-2314 (1994)
Miller SA and Bercaw JE.
Organometallics, 19, 5608-5608 (2000)
Fmoc: a more soluble analogue of the 9-fluorenylmethoxycarbonyl protecting group.
K D Stigers et al.
The Journal of organic chemistry, 65(12), 3858-3860 (2000-06-24)
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