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Merck
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文件

543101

Sigma-Aldrich

乙酸 5-己烯酯

97%

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About This Item

線性公式:
CH3CO2(CH2)4CH=CH2
CAS號碼:
分子量::
142.20
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

化驗

97%

折射率

n20/D 1.423 (lit.)

bp

173-174 °C (lit.)

密度

0.883 g/mL at 25 °C (lit.)

SMILES 字串

CC(=O)OCCCCC=C

InChI

1S/C8H14O2/c1-3-4-5-6-7-10-8(2)9/h3H,1,4-7H2,2H3

InChI 密鑰

MPLWNENKBSBMFN-UHFFFAOYSA-N

一般說明

5-Hexenyl acetate is a linear ester. It can undergo ruthenium-catalyzed cross-metathesis reactions with α-substituted vinyl boronates in dichloromethane. It participates in the post-polymerization modification step during the preparation of poly(vinylnorbornene).

應用

5-Hexenyl acetate may be used in the synthesis of (4E,7Z)-4,7-tridecadienyl acetate.

儲存類別代碼

3 - Flammable liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

141.1 °F - closed cup

閃點(°C)

60.6 °C - closed cup

個人防護裝備

Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)


分析證明 (COA)

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Xicotencatl Camacho-Coronel et al.
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Numerous plant-derived volatile organic compounds (VOCs) induce the expression of resistance-related genes and thereby cause an "associational resistance" in neighbouring plants. However, VOCs can also be sequestered by plant cuticular waxes. In case that they maintain their biological activity, such
Nonconjugated dienes from 1-alkenes: Application to the synthesis of sex pheromone (4E, 7Z)-4, 7-Tridecadienyl acetate
Kim TH and Park KM
Tetrahedron Letters, 36.27, 4833-4836 (1995)
Synthesis of tri-substituted vinyl boronates via ruthenium-catalyzed olefin cross-metathesis
Morrill C, et al.
Tetrahedron Letters, 45.41 , 7733-7736 (2004)
Ring-opening metathesis polymerization of vinylnorbornene and following polymer modifications
Balcar H, et al.
Journal of Polymer Research, 21.9, 1-8 null
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Nature communications, 9(1), 118-118 (2018-01-11)
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