全部照片(1)
About This Item
經驗公式（希爾表示法）:
C13H8BF7S
CAS號碼:
分子量：:
340.07
MDL號碼:
分類程式碼代碼:
12352101
PubChem物質ID:
NACRES:
NA.22
推薦產品
化驗
97%
mp
162-164 °C (lit.)
SMILES 字串
F[B-](F)(F)F.FC(F)(F)[S+]1c2ccccc2-c3ccccc13
InChI
1S/C13H8F3S.BF4/c14-13(15,16)17-11-7-3-1-5-9(11)10-6-2-4-8-12(10)17;2-1(3,4)5/h1-8H;/q+1;-1
InChI 密鑰
VTVISWLINKWMQZ-UHFFFAOYSA-N
應用
- Pd（II）-催化的三氟甲基化
- 铜催化的芳基硼酸三氟甲基化反应（以三甲吡啶为三氟甲基化试剂）
- 芳烃的钯催化亲电邻位三氟甲基化
立体选择性制备用于
- 铜催化末端烯烃三氟甲基化合成三氟甲基取代烯烃
- 钯催化的 α-甲基丙烯分子内脱羧反应-三氟甲基 β-酮酸酯
儲存類別代碼
11 - Combustible Solids
水污染物質分類（WGK）
WGK 3
閃點（°F）
Not applicable
閃點（°C）
Not applicable
個人防護裝備
Eyeshields, Gloves, type N95 (US)
分析證明 (COA)
輸入產品批次/批號來搜索 分析證明 (COA)。在產品’s標籤上找到批次和批號，寫有 ‘Lot’或‘Batch’.。
客戶也查看了
Jun Xu et al.
Chemical communications (Cambridge, England), 47(14), 4300-4302 (2011-03-08)
A copper-catalyzed process for trifluoromethylation of aryl, heteroaryl, and vinyl boronic acids has been developed. The reaction is conducted under mild conditions and shows tolerance to moisture and a variety of functional groups.
Construction of Trifluoromethyl-Bearing Quaternary Carbon Centers by Intramolecular Decarboxylative Allylation of α-Trifluoromethyl β-Keto Esters
Shibata, N.; et al.
Advanced Synthesis & Catalysis, 353, 2037-2041 (2011)
Jun Xu et al.
Journal of the American Chemical Society, 133(39), 15300-15303 (2011-09-15)
An unprecedented type of reaction for Cu-catalyzed trifluoromethylation of terminal alkenes is reported. This reaction represents a rare instance of catalytic trifluoromethylation through C(sp(3))-H activation. It also provides a mechanistically unique example of Cu-catalyzed allylic C-H activation/functionalization. Both experimental and
Xisheng Wang et al.
Journal of the American Chemical Society, 132(11), 3648-3649 (2010-02-27)
A Pd(II)-catalyzed C-H activation/trifluoromethylation of arenes with an electrophilic trifluoromethylation reagent using diverse heterocycle directing groups is reported. The presence of trifluoroacetic acid is crucial for this catalytic reaction.
Xing-Guo Zhang et al.
Journal of the American Chemical Society, 134(29), 11948-11951 (2012-07-12)
A Pd(II)-catalyzed trifluoromethylation of ortho C-H bonds with an array of N-arylbenzamides derived from benzoic acids is reported. N-Methylformamide has been identified as a crucial promoter of C-CF(3) bond formation from the Pd center. X-ray characterization of the C-H insertion
我們的科學家團隊在所有研究領域都有豐富的經驗，包括生命科學、材料科學、化學合成、色譜、分析等.
聯絡技術服務