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Merck
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480835

Sigma-Aldrich

2-溴-4-甲基苯甲醚

97%

同義詞:

3-溴-4-甲氧基甲苯

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About This Item

線性公式:
Br(CH3)C6H3OCH3
CAS號碼:
22002-45-5
分子量：:
201.06
EC號碼:
244-705-3
MDL號碼:
MFCD00017783
分類程式碼代碼:
12352100
PubChem物質ID:
24871722
NACRES:
NA.22

化驗

97%

折射率

n20/D 1.565 (lit.)

bp

124-125 °C/20 mmHg (lit.)

mp

15.5 °C (lit.)

密度

1.392 g/mL at 25 °C (lit.)

SMILES 字串

COc1ccc(C)cc1Br

InChI

1S/C8H9BrO/c1-6-3-4-8(10-2)7(9)5-6/h3-5H,1-2H3

InChI 密鑰

DHPUIKWBNXTXOB-UHFFFAOYSA-N

相關類別

一般說明

2-Bromo-4-methylanisole can be prepared via bromination of 4-methylanisole using poly(4-vinylpyridinium bromochromate).

應用

2-Bromo-4-methylanisole may be used in the synthesis of:
  • 1,6-bis(2-hydroxy-5-methylphenyl)pyridine (H2mdppy)
  • 1,8-dimethoxy-4-methylanthra-quinone
  • ethyl 2-(2-methoxy-5-methylphenyl)-2-methyl-4-oxocyclopentanecarboxylate
It may be used as starting material in the multi-step synthesis of sesquiterpene (±)-herbertenolide.

象形圖

Exclamation mark
GHS07

訊號詞

Warning

危險聲明

H315,H319,H335

危險分類

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

10 - Combustible liquids

水污染物質分類（WGK）

WGK 3

閃點（°F）

235.4 °F - closed cup

閃點（°C）

113 °C - closed cup

個人防護裝備

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

分析證明 (COA)

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Total synthesis of (?)-herbertenolide by stereospecific formation of vicinal quaternary centers in a crystalline ketone.
Ng D, et al.
Organic Letters, 6(4), 645-647 (2004)
Highly efficient white organic electroluminescence from a double-layer device based on a boron hydroxyphenylpyridine complex.
Liu Y, et al.
Angewandte Chemie (International Edition in English), 41(1), 182-184 (2002)
Lipase-Promoted Access to Phenolic Herbertane-Type Sesquiterpenes: (+)-1, 14-Herbertenediol, (-)-a-Herbertenol, (-)-Herbertenediol and Their Enantiomers.
Acherar S, et al.
European Journal of Organic Chemistry, 2004(24), 5092-5099 (2004)
Unambiguous synthesis and spectral characterization of 1,8-dihydroxy-4-methylanthraquinone.
Wang A, et al.
ARKIVOC (Gainesville, FL, United States), 1, 80-84 (2002)
Poly (4-vinylpyridinium bromochromate): an efficient reagent for bromination of aromatic compounds.
Albadi J, et al.
Monatshefte fur Chemie / Chemical Monthly, 144(2), 179-181 (2013)

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