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Merck
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471240

Sigma-Aldrich

N-丁基二乙醇胺

≥98.6%

同義詞:

2,2′-丁基亚氨基二乙醇, N,N-双(2-羟乙基)丁胺

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About This Item

線性公式:
CH3(CH2)3N(CH2CH2OH)2
CAS號碼:
分子量::
161.24
Beilstein:
1739642
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

蒸汽密度

5.5 (vs air)

蒸汽壓力

1 mmHg ( 25 °C)

化驗

≥98.6%

折射率

n20/D 1.463 (lit.)

bp

273-275 °C/741 mmHg (lit.)

mp

−70 °C (lit.)

密度

0.986 g/mL at 25 °C (lit.)

SMILES 字串

CCCCN(CCO)CCO

InChI

1S/C8H19NO2/c1-2-3-4-9(5-7-10)6-8-11/h10-11H,2-8H2,1H3

InChI 密鑰

GVNHOISKXMSMPX-UHFFFAOYSA-N

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一般說明

N -丁基二乙醇胺( N - N -丁基二乙醇胺)是叔胺。作为 N -取代的二乙醇胺配体。它与铬 (II) 和镧系元素 (III)/稀土盐 (Ln = La,Ce,Pr,Nd,Sm,Eu,Gd,Tb,Dy,Ho,Er,Tm,Yb,Lu,Y) 在共配体存在的情况下发生反应,得到 3 个系列的同构 1:1 3d (Cr (III))/4f (Ln (III)) 配位簇化合物。

應用

N-丁基二乙醇胺(H2bdea,N-n-丁基二乙醇胺)已用于合成以下配合物(Hdnba = 3,5-二硝基苯甲酸;Hpta =p-甲苯甲酸;H2tpa =对苯二甲酸):
  • 新单核 [Cu(Hbdea)2]·2Hdnba ,双核[Cu2(β-Hbdea)2(N3)2] 和[Cu2(β-Hbdea)2(pta)2]·2H2O
  • 1D 聚合物 \ [Cu 2 (μHbdea) 2 (μ-tpa)] n ·2nH 2 O 铜 (II) 化合物
  • 四核 3d-4f 单分子磁体 (SMM) 复合物

象形圖

Corrosion

訊號詞

Danger

危險聲明

危險分類

Eye Dam. 1

儲存類別代碼

10 - Combustible liquids

水污染物質分類(WGK)

WGK 1

閃點(°F)

265.1 °F - closed cup

閃點(°C)

129.5 °C - closed cup

個人防護裝備

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


分析證明 (COA)

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Julia Rinck et al.
Inorganic chemistry, 54(7), 3107-3117 (2015-03-11)
Reactions of the N-substituted diethanolamine ligand N-n-butyldiethanolamine with chromium(II) and lanthanide(III)/rare earth salts (Ln = La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Y) in the presence of coligands give access to three series
Stuart K Langley et al.
Inorganic chemistry, 54(7), 3631-3642 (2015-03-24)
Six tetranuclear 3d–4f single-molecule magnet (SMM) complexes formed using N-n-butyldiethanolamine and N-methyldiethanolamine in conjunction with ortho- and para-substituted benzoic acid and hexafluoroacetoacetone ligands yield two families, both having a butterfly metallic core. The first consists of four complexes of type
Katrin R Gruenwald et al.
Dalton transactions (Cambridge, England : 2003), (12)(12), 2109-2120 (2009-03-11)
The new mononuclear [Cu(Hbdea)(2)].2Hdnba (), dinuclear [Cu(2)(mu-Hbdea)(2)(N(3))(2)] () and [Cu(2)(mu-Hbdea)(2)(pta)(2)].2H(2)O (), and 1D polymeric [Cu(2)(mu-Hbdea)(2)(mu-tpa)](n).2nH(2)O () copper(II) compounds have been prepared by self-assembly, in aqueous alkali medium and at ambient conditions, from Cu(II) acetate, N-butyldiethanolamine (H(2)bdea) and the corresponding auxiliary
Giorgio Rizzi et al.
Cell reports, 34(11), 108867-108867 (2021-03-18)
The firing activity of dorso-medial-striatal-cholinergic interneurons (dmCINs) is a neural correlate of classical conditioning. Tonically active, they pause in response to salient stimuli, mediating acquisition of predictive cues/outcome associations. Cortical and thalamic inputs are typical of the rather limited knowledge

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