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Merck
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重要文件

431338

Sigma-Aldrich

硝酸铈(IV)铵

99.99%

同義詞:

硝酸铈铵

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About This Item

線性公式:
Ce(NH4)2(NO3)6
CAS號碼:
分子量::
548.22
EC號碼:
MDL號碼:
分類程式碼代碼:
12352302
PubChem物質ID:

化驗

99.99%

反應適用性

reagent type: oxidant

雜質

≤0.05% insol. dil. H2SO4
<100 ppm total metallic impurities

負離子痕跡

chloride (Cl-): ≤0.01%
phosphate (PO43-): ≤0.02%

正離子痕跡

Fe: ≤0.005%

SMILES 字串

N.N.[Ce+4].O[N+]([O-])=O.O[N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O

InChI

1S/Ce.2HNO3.4NO3.2H3N/c;6*2-1(3)4;;/h;2*(H,2,3,4);;;;;2*1H3/q+4;;;4*-1;;

InChI 密鑰

WIBGOERAEYJBOT-UHFFFAOYSA-N

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應用

提供通过温和条件下氧化丙二酸盐得到丙醇二酸衍生物的一种新途径。

特點和優勢

符合 ACS 试剂规范。

取代透過

產品號碼
描述
訂價

訊號詞

Danger

危險分類

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Met. Corr. 1 - Ox. Sol. 2 - Skin Corr. 1B - Skin Sens. 1A

儲存類別代碼

5.1B - Oxidizing hazardous materials

水污染物質分類(WGK)

WGK 3

個人防護裝備

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges


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Nair, V. et al.
Tetrahedron Letters, 39, 2801-2801 (1998)
Yue Qi Ye et al.
Bioscience, biotechnology, and biochemistry, 74(11), 2342-2344 (2010-11-13)
The structure of a long-known natural pigment, atromentin, was established by a total synthesis based on double Suzuki-Miyaura coupling and by a single-crystal X-ray analysis of the synthetic sample thereby obtained. A similar strategy including ceric ammonium nitrate (CAN) oxidation
D Subhas Bose et al.
Journal of combinatorial chemistry, 12(1), 100-110 (2009-12-17)
An efficient and practical method has been manifested for the diversity-oriented synthesis of quinolines via Friedländer annulation reaction for the generation of a wide range of structurally interesting and pharmacologically significant compounds by using ceric ammonium nitrate as a catalyst
S Sudha et al.
Ultrasonics sonochemistry, 19(5), 994-998 (2012-03-09)
Tetrahydrobenzo[c]xanthenes-11-ones was synthesized by a three component reaction of α-naphthol, aromatic aldehyde and dimedone. Ceric ammonium nitrate acts as a suitable eco-friendly catalyst for this method. Shorter reaction duration, mild reaction condition and low cost make this protocol more effective.
Weibin Song et al.
Bioorganic & medicinal chemistry letters, 22(1), 387-390 (2011-11-26)
A new, practical and efficient method for the synthesis of anhydrovinblastine AVBL (1f) by oxidative coupling of vindoline and catharanthine in the presence of ceric ammonium nitrate (CAN) was developed. Under the optimized reaction conditions, we synthesized a new series

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