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419184

Sigma-Aldrich

三苯基膦二碘化物

technical grade, 90%

同義詞:

二碘三苯基正膦

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About This Item

線性公式:
(C6H5)3PI2
CAS號碼:
分子量::
516.09
Beilstein:
2740417
MDL號碼:
分類程式碼代碼:
12352101
PubChem物質ID:
NACRES:
NA.06

等級

technical grade

化驗

90%

形狀

solid

mp

210-220 °C (lit.)

SMILES 字串

IP(I)(c1ccccc1)(c2ccccc2)c3ccccc3

InChI

1S/C18H15I2P/c19-21(20,16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15H

InChI 密鑰

NSWZEXJQHIXCFL-UHFFFAOYSA-N

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應用

Triphenylphosphine diiodide (Ph3P. I2) can be used as a reagent:
  • To facilitate the conversion of alcohol, thiol, and enol functional groups into alkyl iodides via formation of alkoxyphosphonium iodide.
  • To prepare β-iodo-α,β-unsaturated ketones from cyclic β-diketones in the presence of triethyl amine.
  • In the synthesis of alkyl nitrates from alcohols.
  • In the Beckmann rearrangement reaction to synthesize lactams from cycloalkanone oxime.
  • For the preparation of aromatic and aliphatic carboxylic acid esters in the presence of N,N-dimethylaminopyridine.

Ph3P. I2 can also be used to reduce graphene oxide for the production of graphene nanosheets under mild and environmentally friendly conditions.

象形圖

Health hazardCorrosion

訊號詞

Danger

危險分類

Eye Dam. 1 - Repr. 2 - Resp. Sens. 1 - Skin Corr. 1B - Skin Sens. 1

儲存類別代碼

8A - Combustible corrosive hazardous materials

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


分析證明 (COA)

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存取文件庫

New approach for the reduction of graphene oxide with triphenylphosphine dihalide
Shin H-S et al.
Royal Society of Chemistry Advances, 6(23), 18809-18813 (2016)
Triphenylphosphine-Iodine
Dormoy J-R
Encyclopedia of Reagents for Organic Synthesis, Second Edition (2001)
One-Pot Synthesis of Carboxylic Acid Esters in Neutral and Mild Conditions by Triphenylphosphine Dihalide [Ph 3 PX 2 (X= Br, I)].
Sardarian Alireza R, et al.
Acta Chimica Slovenica, 56(3) (2009)

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