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About This Item
線性公式:
BrC6H3(OCH3)CHO
CAS號碼:
分子量：:
215.04
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22
推薦產品
化驗
98%
mp
51-54 °C (lit.)
SMILES 字串
COc1ccc(C=O)cc1Br
InChI
1S/C8H7BrO2/c1-11-8-3-2-6(5-10)4-7(8)9/h2-5H,1H3
InChI 密鑰
QMPNFQLVIGPNEI-UHFFFAOYSA-N
一般說明
3-Bromo-4-methoxybenzaldehyde is formed by the solvent-free bromination of 4-methoxybenzaldehyde using 1,3-di-n-butylimidazolium tribromide, as a brominating reagent.
應用
3-Bromo-4-methoxybenzaldehyde may be used in the following studies:
- Asymmetric synthesis of a novel β-hydroxy-α-amino acid derivative, via Mukaiyama aldol reaction.
- Synthesis of 2-(3-bromo-4-methoxyphenyl)-5-fluorobenzothiazole.
- Preparation of 5-[(Z)-2-(3-bromo-4-methoxyphenyl)vinyl]-1,2-3-trimethoxybenzene.
- Total synthesis of engelhardione.
- Starting reagent for the synthesis of (2E)-3-(3-bromo-4-methoxyphenyl)-1-(4-methylphenyl)prop-2-en-1-one.
儲存類別代碼
13 - Non Combustible Solids
水污染物質分類（WGK）
WGK 3
閃點（°F）
Not applicable
閃點（°C）
Not applicable
個人防護裝備
Eyeshields, Gloves, type N95 (US)
Li Shen et al.
Tetrahedron letters, 52(35), 4570-4574 (2011-09-20)
The total synthesis of the macrocyclic natural product engelhardione is reported. This effort led to the structural revision of the published structure of engelhardione to that of pterocarine. The revision reflects the change of the substitution pattern of one phenyl
22287813
10th Internatl. Conf. on Organic Synthesis, Bangalore, India, December 1994 null
(2E)-3-(3-Bromo-4-methoxyphenyl)-1-(4-methylphenyl)prop-2-en-1-one.
Dutkiewicz g, et al.
Acta Crystallographica Section E, Structure Reports Online, 67(4), 1024-1024 (2011)
Yali Kong et al.
Chemistry & biology, 12(9), 1007-1014 (2005-09-27)
Targeting the microtubule system represents an attractive strategy for the development of anticancer agents. In this study, we report a class of combretastatin A-4 (CA-4) analogs derivatized with a boronic acid moiety replacing the hydroxyl group on the C-ring of
Aromatic bromination of aldehydes and ketones using 1, 3-di-n-butylimidazolium tribromide [BBIm] Br3 ionic liquids under solvent-free conditions.
Borikar SP and Daniel T.
Journal of the Iranian Chemical Society, 8(2), 531-536 (2011)
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