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Merck
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394483

Sigma-Aldrich

环丁基甲基酮

98%

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About This Item

線性公式:
C4H7COCH3
CAS號碼:
分子量::
98.14
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

化驗

98%

形狀

liquid

折射率

n20/D 1.432 (lit.)

bp

137-139 °C/754 mmHg (lit.)

密度

0.902 g/mL at 25 °C (lit.)

SMILES 字串

CC(=O)C1CCC1

InChI

1S/C6H10O/c1-5(7)6-3-2-4-6/h6H,2-4H2,1H3

InChI 密鑰

JPJOOTWNILDNAW-UHFFFAOYSA-N

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一般說明

Cyclobutyl methyl ketone (CMK, methyl cyclobutyl ketone) is an alicyclic ketone. It has been synthesized by reacting cyclobutanecarbonyl chloride with magnesium salt of malonic ester. The mechanism of the photochemical reaction of gaseous mixtures of cyclobutyl methyl ketone diluted in argon has been studied by steady-state and pulsed (laser) photolysis. It′s infrared (3500 to 30cm-1) and Raman (3200 to 30cm-1) spectra in gaseous and solid state has been recorded. The UV spectra have been measured in alcohol and isooctane solution. Study on the vapour phase thermal and photodecomposition of methyl cyclobutyl ketone shows that the mode of decomposition is free radical in nature.

應用

Cyclobutyl methyl ketone may be used as a model compound to study the oxidation mechanism of pinonic acid by hydroxyl radicals.

象形圖

Flame

訊號詞

Warning

危險聲明

危險分類

Flam. Liq. 3

儲存類別代碼

3 - Flammable liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

84.2 °F - closed cup

閃點(°C)

29 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


分析證明 (COA)

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The Thermal Decomposition of Methyl Cyclobutyl Ketone1,2.
Daignault LG and Walters WD
Journal of the American Chemical Society, 80(3), 541-545 (1958)
The photochemistry of cyclobutyl methyl ketone. Part 1.-Room-temperature results and the general mechanism.
Baldwin PJ, et al
J. Chem. Soc., Faraday II, 83(6), 1049-1058 (1987)
The photochemistry of methyl cyclobutyl ketone. Part 2. Temperature dependence and the acetyl radical decomposition.
Baldwin PJ, et al
International Journal of Chemical Kinetics, 19(11), 997-1013 (1987)
Ultraviolet Absorption Spectra of Alicyclic Compounds. II. Methyl Cycloalkyl Ketones1.
Mariella RP and Raube RR
Journal of the American Chemical Society, 74(2), 518-521 (1952)
Spectra and structure of small ring molecules: Part XLIV. Vibrational spectra and conformational stability of cyclobutylmethyl ketone.
Durig JR, et al
Journal of Molecular Structure, 125(3-4), 211-227 (1984)

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