推薦產品
化驗
98%
形狀
liquid
折射率
n20/D 1.432 (lit.)
bp
137-139 °C/754 mmHg (lit.)
密度
0.902 g/mL at 25 °C (lit.)
SMILES 字串
CC(=O)C1CCC1
InChI
1S/C6H10O/c1-5(7)6-3-2-4-6/h6H,2-4H2,1H3
InChI 密鑰
JPJOOTWNILDNAW-UHFFFAOYSA-N
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一般說明
Cyclobutyl methyl ketone (CMK, methyl cyclobutyl ketone) is an alicyclic ketone. It has been synthesized by reacting cyclobutanecarbonyl chloride with magnesium salt of malonic ester. The mechanism of the photochemical reaction of gaseous mixtures of cyclobutyl methyl ketone diluted in argon has been studied by steady-state and pulsed (laser) photolysis. It′s infrared (3500 to 30cm-1) and Raman (3200 to 30cm-1) spectra in gaseous and solid state has been recorded. The UV spectra have been measured in alcohol and isooctane solution. Study on the vapour phase thermal and photodecomposition of methyl cyclobutyl ketone shows that the mode of decomposition is free radical in nature.
應用
Cyclobutyl methyl ketone may be used as a model compound to study the oxidation mechanism of pinonic acid by hydroxyl radicals.
分析證明 (COA)
輸入產品批次/批號來搜索 分析證明 (COA)。在產品’s標籤上找到批次和批號,寫有 ‘Lot’或‘Batch’.。
The Thermal Decomposition of Methyl Cyclobutyl Ketone1,2.
Journal of the American Chemical Society, 80(3), 541-545 (1958)
The photochemistry of cyclobutyl methyl ketone. Part 1.-Room-temperature results and the general mechanism.
J. Chem. Soc., Faraday II, 83(6), 1049-1058 (1987)
The photochemistry of methyl cyclobutyl ketone. Part 2. Temperature dependence and the acetyl radical decomposition.
International Journal of Chemical Kinetics, 19(11), 997-1013 (1987)
Ultraviolet Absorption Spectra of Alicyclic Compounds. II. Methyl Cycloalkyl Ketones1.
Journal of the American Chemical Society, 74(2), 518-521 (1952)
Spectra and structure of small ring molecules: Part XLIV. Vibrational spectra and conformational stability of cyclobutylmethyl ketone.
Journal of Molecular Structure, 125(3-4), 211-227 (1984)
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