推薦產品
化驗
98%
mp
160-163 °C (lit.)
溶解度
DMSO: soluble 25 mg/mL, clear, yellow
SMILES 字串
O=C1N(Sc2ccccc2)C(=O)c3ccccc13
InChI
1S/C14H9NO2S/c16-13-11-8-4-5-9-12(11)14(17)15(13)18-10-6-2-1-3-7-10/h1-9H
InChI 密鑰
NMHKBABHRKQHOL-UHFFFAOYSA-N
一般說明
N-(Phenylthio)phthalimide is an N-substituted phthalimide. It is used as a sulphenylating agent. The synthesis of N-(phenylthio)phthalimide has been reported.
應用
N-(Phenylthio)phthalimide is suitable reagent used in the synthesis of phenyl (3-trimethoxysilylpropyl)-disulfide. It may be used in the sulfenylation of ylides and β−keto esters.
N-(Phenylthio)phthalimide may be used as sulfenylating agent in the synthesis of the following:
N-(Phenylthio)phthalimide may be used as sulfenylating agent in the synthesis of the following:
- α-phenylthio-ketones and α-phenylthio-aldehydes from aldehydes and ketones
- 3-sulfenyl indoles from indoles
- optically active 3-phenylthiooxindoles from unprotected 3-substituted oxindoles
- N−alkyl-β-phenylsulfenyl-2-acetylbenzimidazole from N−alkyl−2−acetylbenzimidazole
- N−phenylsulfenyl ketimines from oximes or nitro compounds
儲存類別代碼
11 - Combustible Solids
水污染物質分類（WGK）
WGK 3
閃點（°F）
Not applicable
閃點（°C）
Not applicable
The use of anhydrous CeCl3 as a catalyst for the synthesis of 3-sulfenyl indoles.
Silveira CC, et al.
Tetrahedron Letters, 51(15), 2014-2016 (2010)
On the involvement of lipoic acid in. alpha.-keto acid dehydrogenase complexes.
Rastetter WH, et al.
Journal of the American Chemical Society, 101(10), 2752-2753 (1979)
Jordi Burés et al.
Organic letters, 9(22), 4635-4638 (2007-10-09)
As N-sulfenyl imines (e.g., RR'C=N-SAr) can be readily transformed to their N-sulfinyl imines (RR'C=N-SOAr), N-sulfonyl imines (RR'C=N-SO2Ar), and N-sulfonyl oxaziridines, the very mild procedure developed to convert ketoximes and secondary nitro derivatives to N-arenesulfenyl ketimines constitutes a new and efficient
Direct, organocatalytic α-sulfenylation of aldehydes and ketones.
Wang W, et al.
Tetrahedron Letters, 45(44), 8229-8231 (2004)
Quaternized chitosan as an efficient catalyst for synthesis of N-alkylthio-phthalimides.
Hu Z and Li S
International Journal of Chemistry (Canadian Center of Science and Education), 2(2), 213-213 (2010)
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