377392

(R)-(-)-溴化香茅酯

95%

• 同義詞: 8-溴-2,6-二甲基-2-辛烯
• 線性公式: (CH₃)₂C=CHCH₂CH₂CH(CH₃)CH₂CH₂Br
• CAS號碼: 10340-84-8
• 分子量：: 219.16
• MDL號碼: MFCD00134453
• 分類程式碼代碼: 12352101
• PubChem物質ID: 24863501
• NACRES: NA.22

屬性

• 化驗: 95%
• 形狀: liquid
• 光學活性: [α]20/D −6.8°, neat
• 折射率: n20/D 1.474 (lit.)
• bp: 111 °C/12 mmHg (lit.)
• 密度: 1.11 g/mL at 25 °C (lit.)
• 官能基: alkyl halide; bromo
• SMILES 字串: C[C@@H](CCBr)CC\C=C(/C)C
• InChI: 1S/C10H19Br/c1-9(2)5-4-6-10(3)7-8-11/h5,10H,4,6-8H2,1-3H3/t10-/m1/s1
• InChI 密鑰: QPKCDMXLSDFCQD-SNVBAGLBSA-N

描述

應用

(R)-(−)-Citronellylbromide can be used as a reactant to synthesize:

• (R)-3,7-dimethyloct-6-ene-1-amine via Gabriel synthesis which is then condensed with dicarboxylic acids to synthesize retro amides.
• Citronellyl derivatives of sulfoximines and sulfondiimines via alkylation using potassium hydroxide and dimethyl sulfoxide.
• Citronellyltriphenylphosphonium bromide which can be used as a key intermediate to synthesize (+)-caparratriene via Witting reaction.

安全資訊

• 象形圖: GHS07
• 訊號詞: Warning
• 危險聲明: H315,H319,H335
• 防範說明: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• 危險分類: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• 標靶器官: Respiratory system
• 儲存類別代碼: 10 - Combustible liquids
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: 203.0 °F - closed cup
• 閃點（°C）: 95 °C - closed cup
• 個人防護裝備: Eyeshields, Gloves, type ABEK (EN14387) respirator filter