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364533

Sigma-Aldrich

三甲基氟硅烷

96%

同義詞:

Trimethylfluorosilane, 三甲基硅基氟化物

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About This Item

線性公式:
(CH3)3SiF
CAS號碼:
分子量::
92.19
Beilstein:
1731132
EC號碼:
MDL號碼:
分類程式碼代碼:
12142100
PubChem物質ID:

化驗

96%

bp

16 °C (lit.)

mp

−74 °C (lit.)

密度

0.793 g/mL at 25 °C (lit.)

SMILES 字串

C[Si](C)(C)F

InChI

1S/C3H9FSi/c1-5(2,3)4/h1-3H3

InChI 密鑰

CTIKAHQFRQTTAY-UHFFFAOYSA-N

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包裝

Supplied in a Sure/Pac cylinder and has a brass needle valve with a male 1/4" NPTF outlet thread installed. Before using the cylinder, ensure that the valve is closed, then remove the galvanized steel hex cap that seals the outlet valve.

Compatible with the following:

法律資訊

Aldrich is a registered trademark of Sigma-Aldrich Co. LLC
Sure/Pac is a trademark of Sigma-Aldrich Co. LLC

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軟管倒鉤

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訊號詞

Danger

危險分類

Eye Irrit. 2 - Flam. Liq. 1 - Press. Gas Compr. Gas - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

2A - Gases

水污染物質分類(WGK)

WGK 3

閃點(°F)

-22.0 °F - closed cup

閃點(°C)

-30 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves


分析證明 (COA)

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L G Hutchins et al.
The International journal of applied radiation and isotopes, 36(5), 375-378 (1985-05-01)
18F-Labeled fluorotrimethylsilane was prepared by nucleophilic substitution of chlorotrimethylsilane with reactor produced [18F]fluoride. Hydrolysis of fluorotrimethylsilane by aqueous tetraethylammonium hydroxide followed by removal of water with a mechanical pump gave a powerful source of no carrier added nucleophilic 18F. Reaction
M S Rosenthal et al.
The International journal of applied radiation and isotopes, 36(4), 318-319 (1985-04-01)
[18F]Fluorotrimethylsilane was prepared in 80% decay corrected yield by reaction of no-carrier added tetramethyl-ammonium fluoride (hydroxide as bulk anion) with chlorotrimethylsilane in 65% aqueous acetonitrile. The 18F gas was collected in a cold-trap at -130 degrees C and found to
[Gas chromatographic fluoride determination following adsorption of trimethylfluorsilane on Porapak P].
K Seifert
Zeitschrift fur die gesamte Hygiene und ihre Grenzgebiete, 29(2), 80-80 (1983-02-01)
Ian H Krouse et al.
Journal of the American Society for Mass Spectrometry, 16(5), 697-707 (2005-05-03)
In this study, preparation and decomposition of five novel pentavalent fluorosiliconates, RSi(CH3)3F- (R = CH3CH2O, CF3CH2O, (CH3)2CHO, (CH3)3SiO, and (CH3)3SiNH) is used to investigate the process of fluoride-induced desilylation. The siliconates were characterized by collision-induced dissociation and energy-resolved mass spectrometry.
S J Gatley
International journal of radiation applications and instrumentation. Part A, Applied radiation and isotopes, 40(6), 541-544 (1989-01-01)
A flow-through system is described for rapid purification of [18F]fluoride for nucleophilic substitution reactions. It depends on generation of [18F]fluorotrimethylsilane from aqueous 18F solutions and subsequent collection of the gas and its hydrolysis by base in near anhydrous acetonitrile. Potassium

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