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Merck
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重要文件

339636

Sigma-Aldrich

外-N-羟基-7-氧杂二环[2.2.1]庚-5-烯-2,3-二甲酰亚胺

98%

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About This Item

經驗公式(希爾表示法):
C8H7NO4
CAS號碼:
分子量::
181.15
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:

化驗

98%

mp

194 °C (dec.) (lit.)

溶解度

THF: soluble 10 mg/mL, clear, colorless

SMILES 字串

ON1C(=O)[C@H]2C3OC(C=C3)[C@H]2C1=O

InChI

1S/C8H7NO4/c10-7-5-3-1-2-4(13-3)6(5)8(11)9(7)12/h1-6,12H/t3-,4+,5?,6?

InChI 密鑰

PPVGNPSAUJFBJY-LAXKNYFCSA-N

一般說明

exo-N-Hydroxy-7-oxabicyclo[2.2.1]hept-5-ene-2,3-dicarboximide undergoes cross-coupling with aryl boronic acid for ROMP-based O-alkylhydroxylamine parallel synthesis.

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

dust mask type N95 (US), Eyeshields, Gloves


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分析證明 (COA)

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The Diels-Alder reaction is a promising click chemistry for the design of advanced materials from cellulose nanocrystals (CNCs). Transferring such chemistry to cellulose nanocrystals requires the precise grafting of reactive Diels-Alder moeities under heterogeneous conditions without compromising the nanocrystals morphology.
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Journal of combinatorial chemistry, 12(5), 655-658 (2010-09-14)
The parallel synthesis of O-aryloxyamines remains an unfulfilled need in the field of medicinal chemistry and fragment-based approaches. To fill this gap a solution-phase two-step process based on (1) a copper-catalyzed cross-coupling of aryl boronic acids with a fluorous tagged

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