32596

焦碳酸二烯丙基酯

≥95.0% (T)

• 同義詞: (Alloc)₂O, 二烯丙基焦碳酸酯
• 線性公式: (CH₂=CHCH₂OCO)₂O
• CAS號碼: 115491-93-5
• 分子量：: 186.16
• Beilstein: 4390381
• MDL號碼: MFCD00077721
• 分類程式碼代碼: 12352108
• PubChem物質ID: 57648690

屬性

• 化驗: ≥95.0% (T)
• 折射率: n20/D 1.434 (lit.); n20/D 1.434
• bp: 60 °C/0.05 mmHg (lit.)
• 密度: 1.121 g/mL at 25 °C (lit.)
• 應用: peptide synthesis
• 儲存溫度: 2-8°C
• SMILES 字串: C=CCOC(=O)OC(=O)OCC=C
• InChI: 1S/C8H10O5/c1-3-5-11-7(9)13-8(10)12-6-4-2/h3-4H,1-2,5-6H2
• InChI 密鑰: XVSSGIXTKVRGAR-UHFFFAOYSA-N

描述

一般說明

Diallyl pyrocarbonate or (Alloc)₂O is used as a reagent for the introduction of allyloxycarbonyl (Alloc or Aloc) protecting group to primary and secondary amines. In peptide synthesis, it is also used to protect amino acid functional groups due to its stability to the acidic and basic conditions. Various amino functional groups such as amino sugars and nucleosides are also protected by using diallyldicarbonate reagent.

其他說明

便于引入 N-烯丙氧基羰基 (N-Alloc) 氨基保护的试剂；烯丙基氨基甲酸酯保护易受钯(0)试剂裂解。

安全資訊

• 象形圖: GHS07
• 訊號詞: Warning
• 危險聲明: H315,H319,H335
• 防範說明: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• 危險分類: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• 標靶器官: Respiratory system
• 儲存類別代碼: 10 - Combustible liquids
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: 201.2 °F - closed cup
• 閃點（°C）: 94 °C - closed cup
• 個人防護裝備: Eyeshields, Gloves, type ABEK (EN14387) respirator filter