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重要文件

295337

Sigma-Aldrich

三氟甲烷

≥98%

同義詞:

HFC-23, 氟仿

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About This Item

線性公式:
CHF3
CAS號碼:
分子量::
70.01
EC號碼:
MDL號碼:
分類程式碼代碼:
12142100
PubChem物質ID:
NACRES:
NA.22

蒸汽密度

2.43 (vs air)

蒸汽壓力

635 psi ( 21 °C)

化驗

≥98%

bp

−84 °C (lit.)

mp

−160 °C (lit.)

SMILES 字串

FC(F)F

InChI

1S/CHF3/c2-1(3)4/h1H

InChI 密鑰

XPDWGBQVDMORPB-UHFFFAOYSA-N

包裝

Supplied in a carbon steel lecture bottle with a CGA180M/CGA110F needle valve installed.

Compatible with the following:
  • Aldrich® lecture-bottle station systems
  • Aldrich® lecture-bottle gas regulators

其他說明

法律資訊

Aldrich is a registered trademark of Sigma-Aldrich Co. LLC

排氣閥

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描述
訂價

軟管倒鉤

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描述
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象形圖

Gas cylinder

訊號詞

Warning

危險聲明

防範說明

危險分類

Press. Gas Liquefied gas

儲存類別代碼

2A - Gases

水污染物質分類(WGK)

WGK 1

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)


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Naleen B Jayaratna et al.
Inorganic chemistry, 52(4), 1691-1693 (2013-02-02)
Silver and copper ethylene adducts and the silver carbonyl complex of the tris(pyrazolyl)borate [HB(3,4,5-(CF(3))(3)Pz)(3)](-) (which is based on one of the most acidic pyrazoles known) have been synthesized. (13)C NMR resonance signals of metal-bound ethylene carbon atoms of [HB(3,4,5-(CF(3))(3)Pz)(3)]Ag(C(2)H(4)) and
Alessandro Zanardi et al.
Journal of the American Chemical Society, 133(51), 20901-20913 (2011-12-06)
We have found the first reaction of direct cupration of fluoroform, the most attractive CF(3) source for the introduction of the trifluoromethyl group into organic molecules. Treatment of CuX (X = Cl, Br, I) with 2 equiv of MOR (M
Sven P Fritz et al.
Organic letters, 14(24), 6370-6373 (2012-12-13)
CF(3)-substituted vinyl diphenylsulfonium triflate is an effective annulation reagent for the formation of α-CF(3) substituted, epoxide-fused heterocycles (pyrrolidines, piperidines, and tetrahydrofurans). This simple method affords a variety of valuable heterocyclic building blocks in a highly diastereoselective manner (dr >20:1).
Naeem Iqbal et al.
The Journal of organic chemistry, 77(24), 11383-11387 (2012-11-22)
A method for trifluoromethylation of alkenes has been developed employing visible light photoredox catalysis with CF(3)I, Ru(Phen)(3)Cl(2), and DBU. This process works especially well for terminal alkenes to give alkenyl-CF(3) products with only E-stereochemistry. The mild reaction conditions enable the
Nicolas Susperregui et al.
The Journal of organic chemistry, 75(19), 6581-6587 (2010-08-31)
The mechanism of ring-opening of ε-caprolactone by methanol catalyzed by trifluoromethane and methane sulfonic acids has been studied computationally at the DFT level of theory. For both elementary steps, the sulfonic acid was predicted to behave as a bifunctional catalyst.

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