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253901

Sigma-Aldrich

5-溴-1-戊烯

95%

同義詞:

1-溴-4-戊烯, 4-戊烯基溴

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About This Item

線性公式:
Br(CH2)3CH=CH2
CAS號碼:
分子量::
149.03
Beilstein:
506077
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

化驗

95%

形狀

liquid

折射率

n20/D 1.463 (lit.)

bp

126-127 °C/765 mmHg (lit.)

密度

1.258 g/mL at 25 °C (lit.)

儲存溫度

2-8°C

SMILES 字串

BrCCCC=C

InChI

1S/C5H9Br/c1-2-3-4-5-6/h2H,1,3-5H2

InChI 密鑰

LPNANKDXVBMDKE-UHFFFAOYSA-N

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應用

5-溴-1-戊烯用于立体选择性合成 7α-(3-羧丙基) 雌二醇。用于制备具有硫代糖苷键的唾液酸的硫代乙酸酯 11。它还被用作最近合成 DL-组织毒素和含二苯甲酮的脂肪酸的起始材料。

象形圖

FlameExclamation mark

訊號詞

Warning

危險分類

Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

3 - Flammable liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

87.8 °F - closed cup

閃點(°C)

31 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


分析證明 (COA)

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Alkylation of 3,17 beta-bis(2-trimethylsilyl)ethoxymethyl-1,3,5(10) estratriene-6-one (2) with 5-bromo-1-pentene using NaHMDS in THF afforded 3,17 beta-bis(2-trimethylsilyl)ethoxymethyl-7-alpha-(4'pentenyl)-1,3,5(10) estratriene-6-one (3) in excellent stereoselectivity (> 95% epimeric excess). Functionalization of the side chain in compound 3 was accomplished via ozonolysis, oxidation and esterification to

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