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重要文件

247197

Sigma-Aldrich

甲基乙烯基砜

≥97%

同義詞:

1-甲磺酰基乙烯, 乙烯基甲基砜, 甲基乙烯基砜, 甲磺酰乙烯, (甲磺酰基)乙烯

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About This Item

線性公式:
H2C=CHSO2CH3
CAS號碼:
分子量::
106.14
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

化驗

≥97%

形狀

liquid

包含

0.02% p-tert-butylphenol as stabilizer

折射率

n20/D 1.463 (lit.)

bp

115-117 °C/19 mmHg (lit.)

密度

1.212 g/mL at 25 °C (lit.)

官能基

sulfone

儲存溫度

2-8°C

SMILES 字串

CS(=O)(=O)C=C

InChI

1S/C3H6O2S/c1-3-6(2,4)5/h3H,1H2,2H3

InChI 密鑰

WUIJTQZXUURFQU-UHFFFAOYSA-N

基因資訊

應用

已使用甲基乙烯基砜:
  • 作为衍生化试剂的改进方法,使用毛细管 HPLC-质谱法测定核苷混合物中的假尿苷
  • 棉织物迈克尔加成法制备甲基磺酰基乙基纤维素
  • 卤代芳烃的赫克乙烯化

象形圖

Skull and crossbonesCorrosion

訊號詞

Danger

危險聲明

危險分類

Acute Tox. 2 Dermal - Acute Tox. 4 Oral - Eye Dam. 1

儲存類別代碼

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

水污染物質分類(WGK)

WGK 3

閃點(°F)

>235.4 °F - closed cup

閃點(°C)

> 113 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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分析證明 (COA)

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K L Dearfield et al.
Mutagenesis, 6(6), 519-525 (1991-11-01)
Over the past several years, we have been evaluating the mutagenicity and clastogenicity of compounds capable of Michael-type reactions. These compounds, including acrylamide, several acrylate and methacrylate esters, vinyl sulfones, and phorone, have been evaluated using TK+/- -3.7.2C mouse lymphoma
Synthesis, 3495-3495 (2006)
M D Shelby et al.
Mutation research, 250(1-2), 431-437 (1991-09-01)
Methyl vinyl sulfone and divinyl sulfone were tested for the induction of dominant lethal mutations and micronucleated bone-marrow erythrocytes in male mice. These chemicals were chosen for study because of their similarities in structure and chemical reactivity to acrylamide which
Gert Emmerechts et al.
Journal of chromatography. B, Analytical technologies in the biomedical and life sciences, 825(2), 233-238 (2005-07-21)
A method is presented for improved detection of pseudouridine in nucleoside mixtures based on the specific derivatization with methyl vinyl sulfone followed by analysis by capillary HPLC-mass spectrometry. Reaction conditions were optimized in order to obtain the best yield and
G B Gordon et al.
Carcinogenesis, 12(12), 2393-2396 (1991-12-01)
The induction of quinone reductase [QR; NAD(P)H:(quinone acceptor) oxidoreductase; EC 1.6.99.2] in cultured cells and animal tissues of rodents has provided useful information on mechanisms of protection against carcinogens. We have developed a simple and efficient microtiter plate assay for

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