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Merck
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重要文件

232025

Sigma-Aldrich

4-(三氟甲基)苄醇

98%

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About This Item

線性公式:
CF3C6H4CH2OH
CAS號碼:
分子量::
176.14
Beilstein:
1450174
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:

化驗

98%

折射率

n20/D 1.459 (lit.)

bp

78-80 °C/4 mmHg (lit.)

密度

1.286 g/mL at 25 °C (lit.)

SMILES 字串

OCc1ccc(cc1)C(F)(F)F

InChI

1S/C8H7F3O/c9-8(10,11)7-3-1-6(5-12)2-4-7/h1-4,12H,5H2

InChI 密鑰

MOOUWXDQAUXZRG-UHFFFAOYSA-N

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一般說明

Photocatalytic oxidation of 4-(trifluoromethyl)benzyl alcohol to corresponding aldehydes on TiO2 photocatalyst under O2 atmosphere has been reported.

應用

用于(例如)磷酰甲酸酯药物前体和水合铬(IV)的动力学研究的试剂。

象形圖

Exclamation mark

訊號詞

Warning

危險聲明

危險分類

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

10 - Combustible liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

213.8 °F - closed cup

閃點(°C)

101 °C - closed cup

個人防護裝備

Eyeshields, Gloves, type ABEK (EN14387) respirator filter


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分析證明 (COA)

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J. Chem. Soc. Perkin Trans. II, 1145-1145 (1992)
One-pot synthesis of fluorine-containing alkenes from in situ-generated stabilized phosphorus ylides.
Pakravan P, et al.
Phosphorus, Sulfur, and Silicon and the Related Elements, 182(3), 545-549 (2007)
Journal of the American Chemical Society, 114, 4205-4205 (1992)
Selective photocatalytic oxidation of benzyl alcohol and its derivatives into corresponding aldehydes by molecular oxygen on titanium dioxide under visible light irradiation.
Higashimoto S, et al.
J. Catal., 266(2), 279-285 (2009)
E Baciocchi et al.
European journal of biochemistry, 268(3), 665-672 (2001-02-13)
The H(2)O(2)-promoted oxidations of (R)-[alpha-(2)H(1)]-and (S)-[alpha-(2)H(1)]-arylalkanols catalysed by chloroperoxidase (CPO) from Caldariomyces fumago have been investigated. It has been found that with (R)-[alpha-(2)H(1)]-alcohols, the oxidation involves almost exclusively the cleavage of the C-H bond, whereas in the case of the

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