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Merck
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Key Documents

209929

Sigma-Aldrich

2-乙氧基四氢呋喃

99%

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About This Item

經驗公式(希爾表示法):
C6H12O2
CAS號碼:
分子量::
116.16
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:

化驗

99%

形狀

liquid

折射率

n20/D 1.414 (lit.)

bp

170-172 °C (lit.)

密度

0.908 g/mL at 25 °C (lit.)

SMILES 字串

CCOC1CCCO1

InChI

1S/C6H12O2/c1-2-7-6-4-3-5-8-6/h6H,2-5H2,1H3

InChI 密鑰

JQYYUWHWGCJWTN-UHFFFAOYSA-N

一般說明

2-Ethoxytetrahydrofuran undergoes Ln(OTf)3-catalyzed-Povarov coupling reaction with anilines and cyclopentadiene to yield tetrahydroquinolines. Transacetalization of 2-ethoxytetrahydrofuran with various alcohols catalyzed by Fe(ClO4)3 has been reported.

應用

2-Ethoxytetrahydrofuran was used to investigate quantitative, regioselective, O-acylative cleavage of tetrahydrofurans using organic acid halides in the presence of Bi(III) halides.

象形圖

Flame

訊號詞

Danger

危險聲明

危險分類

Flam. Liq. 2

儲存類別代碼

3 - Flammable liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

60.8 °F - closed cup

閃點(°C)

16 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


分析證明 (COA)

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Bi (III) halides as efficient catalysts for the O-acylative cleavage of tetrahydrofurans: an expeditious entry to tetralins.
Coles SJ, et al.
Tetrahedron, 61(18), 4447-4452 (2005)
Lanthanide (III)-catalyzed multi-component aza-Diels-Alder reaction of aliphatic N-arylaldimines with cyclopentadiene.
Powell DA and Batey RA.
Tetrahedron Letters, 44(41), 7569-7573 (2003)
Fe3+-Catalyzed transacetalization of 2-alkoxytetrahydrofurans with alcohols.
Yamanaka D, et al.
Tetrahedron Letters, 49(1), 53-56 (2008)

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