194352

1-甲基-3-哌啶甲酸乙酯

96%

• 同義詞: 3-N-甲基哌啶甲酸乙酯
• 經驗公式（希爾表示法）: C₉H₁₇NO₂
• CAS號碼: 5166-67-6
• 分子量：: 171.24
• Beilstein: 123259
• EC號碼: 225-951-0
• MDL號碼: MFCD00006496
• 分類程式碼代碼: 12352100
• PubChem物質ID: 24851646
• NACRES: NA.22

屬性

• 化驗: 96%
• 折射率: n20/D 1.451 (lit.)
• bp: 88-89 °C/11 mmHg (lit.)
• 密度: 0.954 g/mL at 25 °C (lit.)
• SMILES 字串: CCOC(=O)C1CCCN(C)C1
• InChI: 1S/C9H17NO2/c1-3-12-9(11)8-5-4-6-10(2)7-8/h8H,3-7H2,1-2H3
• InChI 密鑰: VFJJNMLPRDRTCO-UHFFFAOYSA-N

描述

一般說明

Enantiomeric discrimination has been investigated in ¹H and ¹³C NMR spectra of ethyl 1-methyl-3-piperidinecarboxylate in the presence of (-)-(18-crown-6)-2,3,11,12-tetracarboxylic acid.

應用

Reactant for:
N-demethylation of tertiary amines
Reverse cope elimination reactions
Regioselective oxidation
Synthesis of chelating agents
Sequential Michael-Michael-Dieckmann cyclizations

安全資訊

• 象形圖: GHS07
• 訊號詞: Warning
• 危險聲明: H315,H319,H335
• 防範說明: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• 危險分類: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• 標靶器官: Respiratory system
• 儲存類別代碼: 10 - Combustible liquids
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: 154.4 °F - closed cup
• 閃點（°C）: 68 °C - closed cup
• 個人防護裝備: Eyeshields, Gloves, type ABEK (EN14387) respirator filter