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重要文件

171441

Sigma-Aldrich

三氟碘甲烷

99%

同義詞:

三氟甲基碘, 全氟甲基碘, 碘代三氟甲烷

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About This Item

經驗公式(希爾表示法):
CF3I
CAS號碼:
分子量::
195.91
Beilstein:
1732740
EC號碼:
MDL號碼:
分類程式碼代碼:
12142100
PubChem物質ID:
NACRES:
NA.22
化驗:
99%

品質等級

化驗

99%

bp

−22.5 °C (lit.)

mp

<−78 °C (lit.)

官能基

fluoro
iodo

SMILES 字串

FC(F)(F)I

InChI

1S/CF3I/c2-1(3,4)5

InChI 密鑰

VPAYJEUHKVESSD-UHFFFAOYSA-N

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相關類別

應用

用于 α,ß-不饱和酮的铑催化 α-三氟甲基化反应的试剂。

包裝

以Sure/Pac 气瓶供货,并具有配备 1/4" NPTF出口外螺纹的青铜针阀。使用样品筒之前,确保关闭阀门,然后拆下密封出气阀的镀锌钢六角帽。

与以下装置兼容:

法律資訊

Aldrich is a registered trademark of Sigma-Aldrich Co. LLC
Sure/Pac is a trademark of Sigma-Aldrich Co. LLC

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訊號詞

Warning

危險聲明

危險分類

Muta. 2 - Ozone 1 - Press. Gas Compr. Gas

儲存類別代碼

2A - Gases

水污染物質分類(WGK)

WGK 1

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

Eyeshields, Gloves


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分析證明 (COA)

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D E Dodd et al.
Inhalation toxicology, 11(11), 1041-1055 (1999-11-24)
CF(3)I is being considered by the U.S. Air Force as a replacement for Halon 1301 for fire-extinguishing requirements in unoccupied spaces. The purpose of this study was to determine and evaluate the potential for CF(3)I to produce reproductive toxicity and
C Stefan Lehmann et al.
Faraday discussions, 153, 173-187 (2011-01-01)
The control of multichannel ionic fragmentation dynamics in CF3I is studied by femtosecond pulse shaping and velocity map photoelectron photoion coincidence imaging. When CF3I is photoexcited with femtosecond laser pulses around 540 nm there are two major ions observed in
D E Dodd et al.
Fundamental and applied toxicology : official journal of the Society of Toxicology, 35(1), 64-77 (1997-01-01)
Trifluoroiodomethane (CF3I) is being considered as a replacement compound for halon fire suppressants. Its structure is similar to that of Halon 1301 (CF3Br), but it has very low ozone depletion potential compared to CF3Br. As part of the process of
Discovering and verifying elusive fullerene cage isomers: structures of C2-p11-(C74-D3h)(CF3)12 and C2-p11-(C(78)-D3h5)(CF3)12.
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Angewandte Chemie (International ed. in English), 46(22), 4111-4114 (2007-04-25)
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Collision geometry is central to reaction dynamics. An important variable in collision geometry is the miss-distance between molecules, known as the "impact parameter." This is averaged in gas-phase molecular beam studies. By aligning molecules on a surface prior to electron-induced

文章

In 2001, Professor William Dolbier, Jr., at the University of Florida reported1 an approach to nucleophilic trifluoromethylation based on the generation of a trifluoromethyl anion using CF3I in the presence of a powerful twoelectron reductant, tetrakis(dimethylamino)ethylene (TDAE)

2001 年,佛羅里達大學的 William Dolbier, Jr. 教授報告1 了一種親核三氟甲基化學的方法,其基礎是在強大的雙電子還原劑--四(二甲基氨基)乙烯 (TDAE) 的存在下,使用 CF3I 生成三氟甲基負離子。

我們的科學家團隊在所有研究領域都有豐富的經驗,包括生命科學、材料科學、化學合成、色譜、分析等.

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