推薦產品
化驗
98%
形狀
liquid
折射率
n20/D 1.552 (lit.)
bp
183.7 °C (lit.)
mp
−40 °C (lit.)
密度
1.41 g/mL at 25 °C (lit.)
SMILES 字串
Cc1cccc(Br)c1
InChI
1S/C7H7Br/c1-6-3-2-4-7(8)5-6/h2-5H,1H3
InChI 密鑰
WJIFKOVZNJTSGO-UHFFFAOYSA-N
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一般說明
3-溴甲苯是一种富含电子的芳基溴。它可参与Heck反应。 3-溴甲苯在K4[Fe(CN)6](作为氰化物的替代物)的存在下可发生钯催化的氰化反应。 它可与炔基三芳基硼酸酯进行钯催化反应,生成三取代的烯基硼烷。
應用
3-溴甲苯被用于通过MC-ICPMS(多收集器-电感耦合等离子体质谱仪)精确测定有机化合物中的溴同位素比。
訊號詞
Danger
危險分類
Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
標靶器官
Respiratory system
儲存類別代碼
3 - Flammable liquids
水污染物質分類(WGK)
WGK 3
閃點(°F)
140.0 °F
閃點(°C)
60 °C
個人防護裝備
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
分析證明 (COA)
輸入產品批次/批號來搜索 分析證明 (COA)。在產品’s標籤上找到批次和批號,寫有 ‘Lot’或‘Batch’.。
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Chemical communications (Cambridge, England), (42)(42), 4381-4383 (2007-10-25)
The palladium-catalysed reaction of alkynyltriarylborates with aryl halides afforded trisubstituted alkenylboranes, in which two different aryl groups were installed across the carbon-carbon double bond in a cis arrangement.
Heck reaction with an alkenylidenecyclopropane: the formation of arylallylidenecyclopropanes.
Tetrahedron Letters, 48(20), 3579-3581 (2007)
Efficient cyanation of aryl bromides with K4[Fe(CN)6] catalyzed by a palladium-indolylphosphine complex.
Tetrahedron Letters, 52(52), 7038-7041 (2011)
Analytical sciences : the international journal of the Japan Society for Analytical Chemistry, 34(10), 1183-1188 (2018-10-12)
Aryl halides are a very important category of compounds that include many vital drugs and key industrial additives, such as clofibrate and bromobenzene, respectively. Due to their importance, our research group previously developed a novel fluorescence labeling approach for their
文章
Heck反应是烯烃与芳基或乙烯基卤化物(或三氟甲磺酸酯)之间的钯催化交叉偶联反应,用于生成取代的烯烃。
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