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重要文件

148482

Sigma-Aldrich

二苯基硅烷

97%

同義詞:

Diphenyl silane, Diphenylsilicon

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About This Item

線性公式:
(C6H5)2SiH2
CAS號碼:
分子量::
184.31
Beilstein:
2935887
EC號碼:
MDL號碼:
分類程式碼代碼:
12352103
PubChem物質ID:
NACRES:
NA.22

品質等級

化驗

97%

形狀

liquid

折射率

n20/D 1.579 (lit.)

bp

95-97 °C/13 mmHg (lit.)

密度

0.993 g/mL at 25 °C (lit.)

SMILES 字串

[SiH2](c1ccccc1)c2ccccc2

InChI

1S/C12H12Si/c1-3-7-11(8-4-1)13-12-9-5-2-6-10-12/h1-10H,13H2

InChI 密鑰

VDCSGNNYCFPWFK-UHFFFAOYSA-N

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一般說明

二苯基硅烷是子有机硅化合物,可用作酰胺键偶联试剂& 烯烃氢化硅烷化(hydrosilylation)前体。

應用


  • 双二苯基硅烷的制备及其阳离子型UV固化材料性能研究:研究探讨了使用二苯基硅烷的新材料的合成和光敏性,强调了其在UV固化应用中的潜力(Y Liu et al., 2021, MDPI)。

  • 基于双(3,5-二(9H-咔唑-9-基))二苯基硅烷的喷墨打印蓝色磷光发光层:研究使用二苯基硅烷衍生物开发用于喷墨打印的蓝色磷光材料,也可用于电子显示器(R Bail et al., 2018, RSC Advances

儲存類別代碼

10 - Combustible liquids

水污染物質分類(WGK)

WGK 1

閃點(°F)

208.4 °F - closed cup

閃點(°C)

98 °C - closed cup

個人防護裝備

Eyeshields, Gloves, type ABEK (EN14387) respirator filter


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Diphenylsilane as a coupling reagent for amide bond formation
Sayes, Morgane, et al.
Green Chemistry, 19, 5060-5064 (2017)
Saravanan Karuppiah et al.
ACS nano, 14(9), 12006-12015 (2020-09-10)
Silicon (Si) is the most promising anode candidate for the next generation of lithium-ion batteries but difficult to cycle due to its poor electronic conductivity and large volume change during cycling. Nanostructured Si-based materials allow high loading and cycling stability
Ahmad Arar et al.
Molecules (Basel, Switzerland), 25(7) (2020-04-05)
Currently, Redox Initiating Systems (RISs) of Free Radical Polymerization (FRP) are mainly based on the interaction of aromatic amines with peroxides (e.g., dibenzoyl peroxide (BPO)) that can be both toxic and unstable. In the present work, we aim to replace
Slawomir Rubinsztajn et al.
Macromolecular rapid communications, 42(5), e2000601-e2000601 (2020-12-04)
The reaction of poly(hydromethylsiloxane-co-methylphenylsiloxane) with zirconium (IV) n-propoxide in dry toluene leads to extensive scission of the siloxane chain and conversion of Si-H groups. These processes produce oligomeric siloxanes and organosilanes containing moisture sensitive propoxy and siloxy-zirconate groups. The obtained
Christopher L Rock et al.
Dalton transactions (Cambridge, England : 2003), 48(2), 461-467 (2018-11-30)
The phosphine-substituted α-diimine Ni precursor, (Ph2PPrDI)Ni, has been found to catalyze alkene hydrosilylation in the presence of Ph2SiH2 with turnover frequencies of up to 124 h-1 at 25 °C (990 h-1 at 60 °C). Moreover, the selective hydrosilylation of allylic

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