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重要文件

142956

Sigma-Aldrich

2,4-二硝基苯磺酰氯

97%

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About This Item

線性公式:
(O2N)2C6H3SO2Cl
CAS號碼:
分子量::
266.62
Beilstein:
2147583
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

化驗

97%

形狀

solid

mp

101-103 °C (lit.)

官能基

nitro

SMILES 字串

[O-][N+](=O)c1ccc(c(c1)[N+]([O-])=O)S(Cl)(=O)=O

InChI

1S/C6H3ClN2O6S/c7-16(14,15)6-2-1-4(8(10)11)3-5(6)9(12)13/h1-3H

InChI 密鑰

SSFSNKZUKDBPIT-UHFFFAOYSA-N

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一般說明

2,4-二硝基苯磺酰氯引起糖胺发生磺化,产生 N-糖基-2,4-二硝基苯磺酰胺
可能含有高达 3.5% 的苯

應用

2,4-二硝基苯磺酰氯用于保护伯胺。它在合成 2-[((2,4-二硝基苯基)磺酰基]氨基乙酸丁酯中用作起始试剂

象形圖

Health hazardCorrosion

訊號詞

Danger

危險分類

Carc. 1A - Eye Dam. 1 - Muta. 1B - Skin Corr. 1B - STOT RE 2

標靶器官

Blood

儲存類別代碼

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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分析證明 (COA)

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Rachel J Ball et al.
Artificial DNA, PNA & XNA, 1(1), 27-35 (2011-06-21)
Halogen-labelled peptide organic acid (HPOA) monomers have been synthesised and incorporated into sequence-specific peptide nucleic acid (PNA) probes. Three different types of probe have been prepared; the unmodified PNA probe, the PNA probe with a mass marker, and the PNA
Vishwanath Gaitonde et al.
Journal of carbohydrate chemistry, 31(4-6), 353-370 (2013-01-26)
The N-glycosyl-2,4-dinitrobenzenesulfonamides were accessed via benzoyl-protected β-glycosyl azides. The azides were reduced with Adams' catalyst to the corresponding amines. The glycosylamines were sulfonated with 2,4-dinitrobenzenesulfonyl chloride to form N-glycosyl-2,4-dinitrobenzenesulfonamides in moderate yields. β-Glycosyl amides were then prepared in 67 -

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