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135364

Sigma-Aldrich

草酸二乙酯

≥99%

同義詞:

Diethyl ethanedioate, Ethyl oxalate

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About This Item

線性公式:
C2H5OCOCOOC2H5
CAS號碼:
分子量::
146.14
Beilstein:
606350
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

蒸汽密度

5.03 (vs air)

品質等級

蒸汽壓力

1 mmHg ( 47 °C)

化驗

≥99%

形狀

liquid

折射率

n20/D 1.410 (lit.)

bp

185 °C (lit.)

mp

−41 °C (lit.)

溶解度

alcohol: miscible
diethyl ether: miscible
organic solvents: miscible
water: partially soluble

密度

1.076 g/mL at 25 °C (lit.)

SMILES 字串

CCOC(=O)C(=O)OCC

InChI

1S/C6H10O4/c1-3-9-5(7)6(8)10-4-2/h3-4H2,1-2H3

InChI 密鑰

WYACBZDAHNBPPB-UHFFFAOYSA-N

尋找類似的產品? 前往 產品比較指南

一般說明

在非常有效的MoO3/TiO2 固体酸溶胶凝胶催化剂作用下,草酸二乙酯与液相中的苯酚发生酯交换反应,形成草酸二苯酯。它与酮类固醇的活性亚甲基发生Claisen缩合反应,形成乙二醛衍生物。它在高铜含量的中孔Cu/SBA-15催化剂存在下发生氢化反应,生成乙二醇

應用

草酸二乙酯被用于ZnO纳米颗粒的微乳液合成。它还被用于合成 对称-1,4-二苯基-1,4-二氢-1,2,4,5- 聚四吖嗪

訊號詞

Danger

危險聲明

危險分類

Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B - STOT RE 2 Oral

標靶器官

Kidney

儲存類別代碼

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

水污染物質分類(WGK)

WGK 1

閃點(°F)

167.0 °F - closed cup

閃點(°C)

75 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


分析證明 (COA)

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One pot synthesis of ultra-high copper contented Cu/SBA-15 material as excellent catalyst in the hydrogenation of dimethyl oxalate to ethylene glycol.
Guo X, et al.
Catalysis Letters, 132(1-2), 22-27 (2009)
W W Monafo et al.
Surgery, 80(4), 465-473 (1976-10-01)
The wounds of 60 burned patients were treated topically with cerium nitrate, which was applied either as a cream or in aqueous solution. Cerium nitrate has a potent antiseptic effect in human burn wounds, especially against gram negative bacteria and
Novel macromolecules containing sym-tetrazine rings and their subsequent reactions through click modifications.
Sayed RA and Wiggins JS.
Polymer Preprints (American Chemical Society, Division of Polymer Chemistry), 49(1), 188-188 (2008)
Diethyl oxalate as new reagent for spectrophotometric determination of ketosteroids.
S Görög
Analytical chemistry, 42(6), 560-563 (1970-05-01)
Comparison of two novel solution-based routes for the synthesis of equiaxed ZnO nanoparticles.
Elen K, et al.
Journal of Nanomaterials, 2011, 18-18 (2011)

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