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Diflufenican

PESTANAL®, analytical standard

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About This Item

Empirical Formula (Hill Notation):
C19H11F5N2O2
CAS Number:
83164-33-4
Molecular Weight:
394.29
Beilstein:
4212494
MDL number:
MFCD01311804
UNSPSC Code:
41116107
PubChem Substance ID:
329756934
NACRES:
NA.24

grade

analytical standard

Quality Level

100

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

application(s)

agriculture
environmental

format

neat

SMILES string

Fc1ccc(NC(=O)c2cccnc2Oc3cccc(c3)C(F)(F)F)c(F)c1

InChI

1S/C19H11F5N2O2/c20-12-6-7-16(15(21)10-12)26-17(27)14-5-2-8-25-18(14)28-13-4-1-3-11(9-13)19(22,23)24/h1-10H,(H,26,27)

InChI key

WYEHFWKAOXOVJD-UHFFFAOYSA-N

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General description

Diflufenican is a pre- and early post-emergence herbicide used to control dicotyledonous weeds in winter cereals, including Galium aparine, Veronica hederifolia, Veronica persica and Viola arvensis, which are resistant to substituted urea herbicides.

Application

Diflufenican may be used as a reference standard in the determination of diflufenican in water samples using solid-phase microextraction followed by gas chromatography coupled with ion trap-tandem mass spectrometry (SPME-GC-ITD-MS/MS).
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

Pictograms

Exclamation markEnvironment
GHS07,GHS09

Signal Word

Warning

Hazard Statements

H302 + H312,H410

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1

Storage Class Code

11 - Combustible Solids

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number
BCCG3122
BCBT7190
SZBC048XV
SZB7159XV
SZE7159X

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Analytical methods for the determination of isoproturon and diflufenican residues in runoff and soil.
L Patty et al.
Bulletin of environmental contamination and toxicology, 55(6), 802-809 (1995-12-01)
Design and synthesis of N-(2, 4= difluorophenyl)-2-(3-trifluoromethylphenoxy)-3-pyridinecarboxamide (diflufenican), a novel pre-and early post-emergence herbicide for use in winter cereals.
Cramp CM, et al
Pestic. Sci., 18(1), 15-28 (1987)
Umi S Ramli et al.
The New phytologist, 184(2), 330-339 (2009-08-07)
* Oil crops are a very important commodity. Although many genes and enzymes involved in lipid accumulation have been identified, much less is known of regulation of the overall process. To address the latter we have applied metabolic control analysis
V Lecomte et al.
Journal of environmental quality, 30(6), 2113-2119 (2002-01-16)
Because soil surface structure has a considerable influence on infiltration rate, the sealing process is postulated to have a significant effect on herbicide loss through runoff. We evaluated the effect of degraded soil surface structures on herbicide loss in runoff
Analysis of trace levels of pesticides in rainwater using SPME and GC-tandem mass spectrometry.
Scheyer A, et al.
Analytical and Bioanalytical Chemistry, 384(2), 475-487 (2006)
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