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Sigma-Aldrich

Dimethyldiphenylphosphonium iodide

purum, ≥98.0% (AT)

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About This Item

Linear Formula:
(C6H5)2P(I)(CH3)2
CAS Number:
Molecular Weight:
342.16
Beilstein:
3637544
MDL number:
UNSPSC Code:
12352002
PubChem Substance ID:

grade

purum

Assay

≥98.0% (AT)

form

solid

ign. residue

≤2.0%

mp

246-249 °C (lit.)
246-251 °C

SMILES string

[I-].C[P+](C)(c1ccccc1)c2ccccc2

InChI

1S/C14H16P.HI/c1-15(2,13-9-5-3-6-10-13)14-11-7-4-8-12-14;/h3-12H,1-2H3;1H/q+1;/p-1

InChI key

MGLUUYLPGOWCNW-UHFFFAOYSA-M

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Other Notes

The corresponding di-ylide is a powerful reagent for the methylenation of carbonyl compounds; Ylide and di-ylide are used as ligands for organometallic compounds

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Precautionary Statements

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Storage Class Code

13 - Non Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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H.J. Cristau et al.
Phosph. Sulfur Relat. Elem., 30, 135-135 (1987)
H. Schmidbaur et al.
Organometallics, 5, 1652-1652 (1986)
H. Schmidbaur
Accounts of Chemical Research, 8, 62-62 (1975)

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