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667714

Sigma-Aldrich

Borane-d3-THF complex solution

1.0 M in THF, contains 0.005 M N-Isopropyl-N-methyl-tert-butylamine as stabilizer, 97.5 atom % D (mimimum)

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About This Item

Empirical Formula (Hill Notation):
BD3 · C4H8O
Molecular Weight:
88.96
MDL number:
UNSPSC Code:
12352005
PubChem Substance ID:

isotopic purity

97.5 atom % D (mimimum)

contains

0.005 M N-Isopropyl-N-methyl-tert-butylamine as stabilizer

reaction suitability

reagent type: reductant

concentration

1.0 M in THF

impurities

<5% ethyl ether

density

0.881 g/mL at 25 °C

mass shift

M+3

storage temp.

2-8°C

SMILES string

[2H]B([2H])[2H].C1CCOC1

InChI

1S/C4H8O.BH3/c1-2-4-5-3-1;/h1-4H2;1H3/i;1D3

InChI key

RMCYTHFAWCWRFA-SVLQTQOOSA-N

Application

THF solution of borane-d3 stabilized with N-isopropyl-N-methyl tert-butylamine used for the preparation of isotopically labeled alcohols.

Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - STOT SE 3 - Water-react 1

Target Organs

Central nervous system, Respiratory system

Supplementary Hazards

Storage Class Code

4.3 - Hazardous materials which set free flammable gases upon contact with water

WGK

WGK 2

Flash Point(F)

1.4 °F - closed cup

Flash Point(C)

-17 °C - closed cup


Certificates of Analysis (COA)

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Tetrahedron Letters, 48, 2335-2335 (2007)

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