Skip to Content
Merck
All Photos(1)

Key Documents

View All Documentation

536245

Sigma-Aldrich

(+)-2,3-Cyclohexylidene-L-erythruronic acid

96%

Sign Into View Organizational & Contract Pricing
All Photos(1)

About This Item

Empirical Formula (Hill Notation):
C10H14O5
CAS Number:
85281-85-2
Molecular Weight:
214.22
Beilstein:
5338165
MDL number:
MFCD09998203
UNSPSC Code:
12352005
PubChem Substance ID:
24878145
NACRES:
NA.22

Assay

96%

optical activity

[α]20/D −10°, c = 1 in methanol

mp

102-105 °C (lit.)

SMILES string

OC1OC(=O)[C@@H]2OC3(CCCCC3)O[C@H]12

InChI

1S/C10H14O5/c11-8-6-7(9(12)13-8)15-10(14-6)4-2-1-3-5-10/h6-8,11H,1-5H2/t6-,7+,8?/m0/s1

InChI key

GHGRKHAVPBZSIH-KJFJCRTCSA-N

Looking for similar products? Visit Product Comparison Guide

Application

(+)-2,3-Cyclohexylidene-L-erythruronic acid can be used as a starting material to prepare (2R,3S)-1,4-bis(diphenylphosphino)butane-2,3-diol ligand, which is further used to synthesize Rh(I) based catalyst for the hydrogenation of olefins.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number
08125MI
00605TI

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Search for a COA

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Cooperative attractive interactions in asymmetric hydrogenations with dihydroxydiphosphine Rh (I) catalysts-a competition study
Holz J, et al.
Journal of Organometallic Chemistry, 603(1), 61-68 (2000)

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service