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440272

Sigma-Aldrich

Dichlorodimethylsilane

≥99.5%

Synonym(s):

DMDCS, Dimethyldichlorosilane

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About This Item

Linear Formula:
(CH3)2SiCl2
CAS Number:
75-78-5
Molecular Weight:
129.06
Beilstein:
605287
EC Number:
200-901-0
MDL number:
MFCD00000491
UNSPSC Code:
12352103
PubChem Substance ID:
24867582
NACRES:
NA.22

Assay

≥99.5%

form

liquid

refractive index

n20/D 1.404 (lit.)

bp

70 °C (lit.)

mp

−76 °C (lit.)

density

1.07 g/mL at 25 °C (lit.)

storage temp.

2-8°C

SMILES string

C[Si](C)(Cl)Cl

InChI

1S/C2H6Cl2Si/c1-5(2,3)4/h1-2H3

InChI key

LIKFHECYJZWXFJ-UHFFFAOYSA-N

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Application

Common reagent for synthesis of optically active ansa-mettallocene polymerization catalysts.
Used to prepare a resin bound siloxane with reactivity towards tertiary alcohols.

Packaging

View returnable container options.

Signal Word

Danger

Hazard Statements

H225,H302,H314,H331,H335

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1A - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

3 - Flammable liquids

WGK

WGK 1

Flash Point(F)

33.8 °F - closed cup

Flash Point(C)

1 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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Tetrahedron, 63, 299-299 (2007)
Cliff R Baar et al.
Journal of the American Chemical Society, 126(26), 8216-8231 (2004-07-01)
A series of enantiopure C1-symmetric metallocenes, [(SiMe2)2[eta5-C5H(CHMe2)2][eta5-C5H2((S)-CHMeCMe3)]]ZrCl2, (S)-2, [(SiMe2)2[eta5-C5H(CHEt2)2][eta5-C5H2((S)-CHMeCMe3)]]ZrCl2, (S)-6, and [(SiMe2)2[eta5-C5HCy2][eta5-C5H2((S)-CHMeCMe3)]]ZrCl2, (S)-7 (Cy = cyclohexyl), zirconocene dichlorides that have an enantiopure methylneopentyl substituent on the "upper" cyclopentadienyl ligand, and diastereomerically pure precatalysts, [(SiMe2)2[eta5-C5H((S)-CHMeCy)(CHMe2)][eta5-C5H3]]ZrCl2, (S)-8a and (S)-8b, which have an
S N Krylov et al.
Electrophoresis, 21(4), 767-773 (2000-03-25)
Capillary electrophoresis (CE) is an important tool of chemical cytometry. Whole-cell analysis using CE starts with cell injection into the capillary by either siphoning or electroosmosis. However, strong adherence of the cell to the support surface can prevent efficient cell
Y C Tseng et al.
Biomaterials, 16(13), 963-972 (1995-09-01)
Amphipathic ethylene glycol-butadiene block copolymers (PEG-PB) with different chain lengths of poly(ethylene glycol) (PEG) were synthesized by reacting poly(ethylene glycol methyl ether) (m-PEG, mol. wt = 350, 550, 750, 2000 and 5000) with telechelic polybutadiene (PB). The PEG-PB copolymers formed
Zhanhui Wang et al.
Journal of biochemical and biophysical methods, 57(3), 203-211 (2003-09-27)
The feasibility of using protein A to immobilize antibody on silicon surface for a biosensor with imaging ellipsometry was presented in this study. The amount of human IgG bound with anti-IgG immobilized by the protein A on silicon surface was
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