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298190

Sigma-Aldrich

Cerium(III) chloride

AnhydroBeads, −10 mesh, 99.9%

Synonym(s):

Cerium trichloride, Cerous chloride

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About This Item

Empirical Formula (Hill Notation):
CeCl3
CAS Number:
Molecular Weight:
246.48
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.23

product line

AnhydroBeads

Assay

99.9%

reaction suitability

reagent type: catalyst
core: cerium

impurities

≤1500.0 ppm Trace Rare Earth Analysis

particle size

−10 mesh

mp

848 °C (lit.)

density

3.97 g/mL at 25 °C (lit.)

SMILES string

Cl[Ce](Cl)Cl

InChI

1S/Ce.3ClH/h;3*1H/q+3;;;/p-3

InChI key

VYLVYHXQOHJDJL-UHFFFAOYSA-K

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Application

When added to nitrile aldol reactions, diastereoselectivity is enhanced, providing high yields of β-hydroxynitriles.

Legal Information

AnhydroBeads is a trademark of Sigma-Aldrich Co. LLC

Pictograms

CorrosionEnvironment

Signal Word

Danger

Hazard Statements

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Corr. 1C

Storage Class Code

8B - Non-combustible corrosive hazardous materials

WGK

WGK 2

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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David Schneider et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 23(50), 12243-12252 (2017-03-24)
A series of heteroleptic tris(cyclopentadienyl) Ce
Xiao, Z. Timberlake, J.W.
Tetrahedron, 54, 4211-4211 (1998)
Yanfang Wu et al.
Chemosphere, 74(9), 1260-1265 (2008-12-17)
Using both histochemical and cytochemical methods, we investigated the effects of copper (Cu) on the production of hydrogen peroxide (H2O2) and superoxide anion (O2(.-)) in the leaves of the moss Plagiomnium cuspidatum. Cu treatment significantly increased the contents of total
Xiaoming Tao et al.
Organic letters, 15(1), 72-75 (2012-12-25)
Dynamic kinetic resolution of various α-amido-β-keto phosphonates via asymmetric hydrogenation proceeded efficiently to give the corresponding β-hydroxy-α-amido phosphonates in high diastereo- and enantioselectivities (up to 99:1 syn/anti, 99.8% ee). The addition of catalytic amounts of CeCl(3)·7H(2)O is necessary to achieve
Masami Kawagoe et al.
Journal of trace elements in medicine and biology : organ of the Society for Minerals and Trace Elements (GMS), 22(1), 59-65 (2008-03-06)
We evaluated tissue changes associated with cerium chloride administration via gavage to adult mice, via milk to neonatal mice and transplacentally to fetal mice. Change in adults consisted of extensive pulmonary hemorrhage, pulmonary venous congestion, thickened alveolar septae, hepatic necrosis

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