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74886

Supelco

Sodium 1-octanesulfonate solution

suitable for ion pair chromatography, LiChropur™, concentrate, ampule

Synonym(s):

1-Octanesulfonic acid sodium salt

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About This Item

Linear Formula:
CH3(CH2)6CH2SO3Na
CAS Number:
5324-84-5
Molecular Weight:
216.27
Beilstein:
3574241
MDL number:
MFCD00007544
UNSPSC Code:
12000000
PubChem Substance ID:
329765940
NACRES:
NB.21

Quality Level

100

form

liquid

quality

LiChropur™
ampule

packaging

ampule of 25 mL

technique(s)

ion pair chromatography: suitable

λ

in concentrate

UV absorption

λ: 210 nm Amax: 0.08
λ: 220 nm Amax: 0.05
λ: 230 nm Amax: 0.03
λ: 260 nm Amax: 0.02
λ: 500 nm Amax: 0.02

suitability

corresponds to standard for RP gradient test
corresponds to standard for filter test

SMILES string

[Na+].CCCCCCCCS([O-])(=O)=O

InChI

1S/C8H18O3S.Na/c1-2-3-4-5-6-7-8-12(9,10)11;/h2-8H2,1H3,(H,9,10,11);/q;+1/p-1

InChI key

HRQDCDQDOPSGBR-UHFFFAOYSA-M

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General description

Concentrate for 6x1 L ready-to-use solution. Dilute contents of one ampule (~0.3 M) to 1 L with HPLC grade water to obtain a 0.005 M eluent solution.
Sodium 1-octanesulfonate monohydrate (NaOS) is an ion-pairing reagent.

Application

NaOS has been used as ion-pairing reagent for ultra-high performance liquid chromatography (UPLC) analysis with photodiode array detection to estimate paraquat (methyl viologen) in tissue homogenate. It may also be used in determination of dopamine and its metabolites in brain microdialysates using liquid chromatography combined with electrospray ionization tandem mass spectrometry (LC–ESI-MS/MS).

Legal Information

LiChropur is a trademark of Merck KGaA, Darmstadt, Germany

Pictograms

Corrosion
GHS05

Signal Word

Danger

Hazard Statements

H314

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
BCCF8165
BCCC8099
BCBW2039
BCBV1413
BCBR7899V

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Sigma-Aldrich

D3412

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Rapid and simple analysis of paraquat in tissue homogenate by ultra-high performance liquid chromatography.
Merritt, T. J. S., et al.
Analytical Methods : Advancing Methods and Applications, 3.6, 1428-1432 (2011)
Tejwant Singh et al.
Physical chemistry chemical physics : PCCP, 12(37), 11728-11735 (2010-08-10)
We have observed dual transitions in various physical properties while investigating the surfactant-like behavior of the ionic liquid (IL) 1-butyl-3-methylimidazolium octylsulfate [C(4)mim][C(8)SO(4)] in aqueous media. Interestingly, in conductivity measurements, it was found that the second transition, which is comparatively weak
P G Jaison et al.
Journal of chromatography. A, 1216(9), 1383-1389 (2009-01-27)
Studies were carried out for the separation of uranium (U) and thorium (Th) on reversed-phase (RP) C18 columns using mandelic acid as an eluent. Retention of thorium-mandelate on the unmodified stationary phase was found to be greater than that of
I T James et al.
Journal of chromatography, 525(1), 43-57 (1990-01-26)
Following a detailed study, a rapid and sensitive assay for the naturally fluorescent collagen cross-links pyridinoline and deoxypyridinoline has been developed using ion-pair reversed-phase high-performance liquid chromatography in the presence of 1-octanesulphonic acid (OSA). Pyridinoline and deoxypyridinoline were separated on
Yingjie Ma et al.
Chemical communications (Cambridge, England), 47(45), 12340-12342 (2011-10-21)
By the introduction of trimethylammonium groups at both upper and lower rims, a cationic water-soluble pillar[5]arene was prepared, which forms a stable 1 : 1 host-guest complex with sodium 1-octanesulfonate in water.
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