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697583

Sigma-Aldrich

(1S,2S)-(2-Amino-1-phenylpropyl)diphenylphosphine

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Synonym(s):

(1S,2S)-(2-Diphenylphosphino)-1-methyl-2-phenylethylamine

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About This Item

Empirical Formula (Hill Notation):
C21H22NP
CAS Number:
Molecular Weight:
319.38
MDL number:
UNSPSC Code:
12352116
PubChem Substance ID:
NACRES:
NA.22

form

solid

optical activity

[α]22/D +116°, c = 0.5 in chloroform

mp

100-105 °C

functional group

amine
phenyl
phosphine

SMILES string

C[C@H](N)[C@@H](P(c1ccccc1)c2ccccc2)c3ccccc3

InChI

1S/C21H22NP/c1-17(22)21(18-11-5-2-6-12-18)23(19-13-7-3-8-14-19)20-15-9-4-10-16-20/h2-17,21H,22H2,1H3/t17-,21+/m0/s1

InChI key

JWZAIGGNEGTDMG-LAUBAEHRSA-N

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Legal Information

Sold under license from Kanata Chemical Technologies Inc. for research purposes only.

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Articles

An increased interest in aminophosphine type ligands used for asymmetric synthesis has been witnessed. This growth in popularity of aminophosphine ligands in asymmetric synthesis is in part due to the growing number of convenient synthetic pathways leading to useful ligand sets.

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