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CRM69090

Supelco

Chlordimeform

certified reference material, TraceCERT®, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland

Synonym(s):

N-(4-Chloro-2-methylphenyl)-N′,N′-dimethylformamidine, Chlorodimeform, Chlorophenamidine

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About This Item

Empirical Formula (Hill Notation):
C10H13ClN2
CAS Number:
Molecular Weight:
196.68
Beilstein:
9256367
MDL number:
UNSPSC Code:
41116107
NACRES:
NA.24

grade

certified reference material
TraceCERT®

Quality Level

product line

TraceCERT®

shelf life

limited shelf life, expiry date on the label

manufacturer/tradename

Manufactured by: Sigma-Aldrich Production GmbH, Switzerland

storage temp.

-10 to -25°C

SMILES string

CN(C)\C=N\c1ccc(Cl)cc1C

InChI

1S/C10H13ClN2/c1-8-6-9(11)4-5-10(8)12-7-13(2)3/h4-7H,1-3H3/b12-7+

InChI key

STUSTWKEFDQFFZ-KPKJPENVSA-N

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General description

This certified reference material (CRM) is produced and certified in accordance with ISO/IEC 17025 and ISO 17034. This CRM is traceable to primary material from an NMI, e.g. NIST or NMIJ.
Certified content by quantitative NMR incl. uncertainty and expiry date are given on the certificate.
Download your certificate at: http://www.sigma-aldrich.com
Chlordimeform- a formamidine insecticide and acaricide, is used to protect fruits, crops such as cotton, livestock, and pets. It acts by activating the octopamine receptors in the insects. It is not approved for its use in the European Union as a plant protection product.

Application

The certified reference material (CRM) is intended to be used as a calibrant for chromatography and other analytical techniques.
The chlordimeform CRM may also be used to:
  • Develop and validate a method for simultaneous determination of amitraz, chlordimeform, formetanate, and their 5 metabolites in human urine samples by high performance liquid chromatography-tandem mass spectrometry (HPLC-MS/MS) technique
  • Determine formamidine pesticides and their main metabolites in blood samples by using core shell columns for liquid chromatographic (LC) separation and tandem mass spectrometry (MS/MS) for detection in multiple reaction monitoring (MRM) mode
  • Analyze residues of 74 pesticides from different classes, in samples of traditional medicines of Chuanxiong and Danggui by acetate QuEChERS method for extraction and gas chromatography-tandem mass spectrometry (GC-MS/MS) for detection
  • Quantify 106 pesticide residues in nut samples by using microwave-assisted solvent extraction to extract pesticides, combining freeze-out with dispersive solid-phase extraction for clean-up, and ultra-high pressure liquid chromatography-tandem mass spectrometry(UHPLC-MS/MS)
  • Prepare samples of fruits and vegetables by Fe3O4 magnetic nanoparticles (MNPs) based QuEChERS method to determine multiple pesticide residues by gas chromatography-tandem mass spectrometry (GC-MS/MS)
  • Simultaneously determine 284 environmental contaminants in human fat tissue samples by gas chromatography-tandem mass spectrometry (GC-MS/MS)

Recommended products

Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.

Legal Information

TraceCERT is a registered trademark of Merck KGaA, Darmstadt, Germany

Signal Word

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 2 - Eye Dam. 1

Storage Class Code

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


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Na Wang et al.
Journal of chromatography. B, Analytical technologies in the biomedical and life sciences, 898, 38-52 (2012-05-02)
This paper describes a method for the simultaneous determination of 284 environmental contaminants, including 57 pesticides, 15 polycyclic aromatic hydrocarbons (PAHs), 209 polychlorinated biphenyls (PCBs) and 3 phthalate esters (PAEs), in adipose tissue samples. For the first time, a gas
Xue Gao et al.
Journal of chromatography. B, Analytical technologies in the biomedical and life sciences, 1052, 27-33 (2017-03-28)
A rapid, simple and reliable high performance liquid chromatography-tandem mass spectrometry (HPLC-MS/MS) method was developed for simultaneous determination of amitraz, chlordimeform, formetanate and their main metabolites, N-(2,4-dimethylphenyl)-N-methyl-formamidine (DMPF), 2,4-dimethylformamidine (DMF), 2,4-dimethylaniline (DMA), 4-chloro-2-methylaniline and 3-hydroxyacetanilide in human urine. The urine
Jingjing Wang et al.
Journal of separation science, 40(11), 2398-2405 (2017-04-05)
As a result of the low water content and high fat matrices in nuts, it is very difficult to simultaneously determine multi-pesticides in trace levels. Here, a sample pretreatment method was developed in which, microwave-assisted solvent extraction was firstly used
Yuhong Wu et al.
Journal of chromatography. B, Analytical technologies in the biomedical and life sciences, 1076, 22-28 (2018-02-07)
A number of poisoning and suicide cases involving formamidine pesticides have been reported, thus developing a rapid and low cost determination method is crucial. In this work, a rapid, sensitive and low-cost method for the simultaneous determination of formamidine pesticides
Yan-Fei Li et al.
Journal of chromatography. A, 1361, 77-87 (2014-08-26)
Based on a modified quick, easy, cheap, effective, rugged and safe (QuEChERS) sample preparation method with Fe3O4 magnetic nanoparticles (MNPs) as the adsorbing material and gas chromatography-tandem mass spectrometry (GC-MS/MS) determination in multiple reaction monitoring (MRM) mode, we established a

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