659452

1-Adamantanethiol

95%

• Sinónimos: 1-AD, 1-AdSH, 1-AdmSH
• Fórmula empírica (notación de Hill): C₁₀H₁₆S
• Número de CAS: 34301-54-7
• Peso molecular: 168.30
• MDL number: MFCD00213530
• UNSPSC Code: 12352103
• PubChem Substance ID: 24884424
• NACRES: NA.23

Propiedades

• assay: 95%
• form: solid
• mp: 99-106 °C
• SMILES string: SC12C[C@H]3C[C@H](C[C@H](C3)C1)C2
• InChI: 1S/C10H16S/c11-10-4-7-1-8(5-10)3-9(2-7)6-10/h7-9,11H,1-6H2/t7-,8+,9-,10-
• InChI key: ADJJLNODXLXTIH-CHIWXEEVSA-N

Descripción

General description

1-Adamantanethiol (AT) is a bulky caged hydrocarbon based thiol that has no free rotational configurations in its backbone. It forms a self-assembled monolayer (SAM) by attaching order close packed structured to the surface atoms.

Application

Displaceable Monolayers and Microdisplacement Printing: 1-Adamantanethiol Assembly and Applications

AT can be used to functionalize folic acid based polyethylene glycol-maleimide which can be used in the development of gold nanorod (AuNR) based mixtures for spatiotemporal delivery of anticancer therapeutics. It can also be used with 1-octadecanethiol which forms SAM on palladium/aluminum oxide (Pd/Al₂O₃) which finds potential application as a controlled catalyst.

Reagent used to prepare 1-adamantylthio sialosides for glycosylation with mono- and oligosaccharides on treatment with NIS in triflic acid.

Información de seguridad

• pictograms: GHS06
• signalword: Danger
• hcodes: H301,H319
• pcodes: P301 + P310 + P330 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 3 Oral - Eye Irrit. 2
• Storage Class: 6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges