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Merck

CRM67566

Supelco

精甲霜灵

certified reference material, TraceCERT®, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland

别名:

N-(2,6-二甲苯基)-N-(甲氧基乙酰基)-D-丙氨酸甲酯, 精甲霜灵

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About This Item

经验公式(希尔记法):
C15H21NO4
CAS号:
分子量:
279.33
MDL號碼:
分類程式碼代碼:
41116107
NACRES:
NA.24

等級

certified reference material
TraceCERT®

品質等級

產品線

TraceCERT®

儲存期限

limited shelf life, expiry date on the label

製造商/商標名

Manufactured by: Sigma-Aldrich Production GmbH, Switzerland

SMILES 字串

COCC(=O)N([C@H](C)C(=O)OC)c1c(C)cccc1C

InChI

1S/C15H21NO4/c1-10-7-6-8-11(2)14(10)16(13(17)9-19-4)12(3)15(18)20-5/h6-8,12H,9H2,1-5H3/t12-/m1/s1

InChI 密鑰

ZQEIXNIJLIKNTD-GFCCVEGCSA-N

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相关类别

一般說明

This certified reference material (CRM) is produced and certified in accordance with ISO/IEC 17025 and ISO 17034. This CRM is traceable to primary material from an NMI, e.g. NIST or NMIJ.
Certified content by quantitative NMR incl. uncertainty and expiry date are given on the certificate.
Download your certificate at: http://www.sigma-aldrich.com
Metalaxyl-M is the R-enantiomer of the systemic fungicide metalaxyl. It is a widely used acetylalanine fungicide.
As per Regulation (EC) No. 1107/2009, repealing directive 91/414/EEC, metalaxyl-M is approved for use as a plant protection agent in the European Union. The Commission Regulation (EU) 2020/617 of 5th May 2020 renewed the approval of use for metalaxyl-M in products of plant origin until 31st May 2035. The Reg. (EU) 2017/1164 sets a maximum residue limit (MRL) of 0.7 mg/kg and 0.01 mg/kg in fresh/frozen fruits and tree nuts respectively for metalaxyl including other mixtures of constituent isomers including metalaxyl-M (sum of isomers).
Metalaxyl-M has to be monitored in the Multiannual Control Programme for Pesticides Residues (MACP), run within the EU and EFTA in/on products of plant origin.

應用

The certified reference material (CRM) is intended to be used as a calibrant for chromatography and other analytical techniques.
The metalaxyl-M CRM may also find following uses:
  • Mixed-mode solid phase extraction (SPE) and liquid chromatographic-mass spectrometric (LC-MS) determination of 9 fungicides in red and white wine samples
  • Analyze the uptake and distribution of two fungicides and two insecticides in greenhouse grown chrysanthemum by QuEChERS-based extraction from the root, stem, leaf, flower, and soil samples, followed by an UPLC-MS/MS determination
  • Simultaneous determination of six fungicides residues in grape, wine, and raisin samples by HPLC-MS/MS
  • Separation of 21 chiral pesticides by supercritical fluid chromatography-mass spectrometry (SFC-ESIMS/MS) from tomato, orange, leek, and cayenne samples
  • Investigation of 109 pesticide residues in gherkin samples by liquid chromatography-tandem mass spectrometry (LC-MS/MS) and gas chromatography-tandem mass spectrometry (GC-MS/MS)
  • Multi-residue analysis of 58 pesticide residues in water samples by extraction using solvent-based de-emulsification dispersive liquid-liquid microextraction (SD-DLLME) and determination by liquid chromatography-tandem mass spectrometry (LC-MS/MS)

法律資訊

TraceCERT is a registered trademark of Merck KGaA, Darmstadt, Germany

象形圖

CorrosionExclamation mark

訊號詞

Danger

危險聲明

危險分類

Acute Tox. 4 Oral - Eye Dam. 1

儲存類別代碼

10 - Combustible liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable


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分析证书(COA)

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Víctor Cutillas et al.
Journal of chromatography. A, 1620, 461007-461007 (2020-03-11)
Evaluation of chiral pesticides remains a frequently neglected matter in routine food control laboratories. This fact is due to the existence of many residue definitions but also due to the lack of robust instrumental methods for the evaluation of these
I Carpinteiro et al.
Journal of chromatography. A, 1217(48), 7484-7492 (2010-10-26)
A novel procedure for the determination of nine selected fungicides (metalaxyl-M, azoxystrobin, myclobutanil, flusilazole, penconazole, tebuconazole, propiconazole, diniconazole and difenoconazole) in wine samples is presented. Sample enrichment and purification is simultaneously performed using mixed-mode, anion exchange and reversed-phase, OASIS MAX
Quantification of pesticide residues in gherkins by liquid and gas chromatography coupled to tandem mass spectrometry
Golge O, et al.
Journal of food composition and analysis, 96, 103755-103755 (2021)
Rapid analysis and residue evaluation of six fungicides in grape wine-making and drying
Hou X, et al.
Journal of food composition and analysis, 89, 103465-103465 (2020)
Effects of the chiral fungicides metalaxyl and metalaxyl-M on the earthworm Eisenia fetida as determined by 1H-NMR-based untargeted metabolomics
Zhang R and Zhou Z
Molecules (Basel), 24(7), 1293-1293 (2019)

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