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Merck

83352

Sigma-Aldrich

乙酸汞

puriss. p.a., ACS reagent, ≥99.0% (precipitation titration)

别名:

醋酸汞

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50 G
$207.00
250 G
$731.00

About This Item

线性分子式:
(CH3COO)2Hg
CAS号:
分子量:
318.68
Beilstein:
3563831
EC 号:
MDL编号:
UNSPSC代码:
12352103
PubChem化学物质编号:
NACRES:
NB.24

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等级

ACS reagent
puriss. p.a.

方案

≥99.0% (precipitation titration)

表单

powder or crystals

灼烧残渣(还原后)

≤0.02%

mp

179-182 °C (lit.)

溶解性

water: soluble(lit.)

痕量阴离子

chloride (Cl-): ≤50 mg/kg
nitrate (NO3-): ≤50 mg/kg
sulfate (SO42-): ≤50 mg/kg

痕量阳离子

Ca: ≤10 mg/kg
Cd: ≤5 mg/kg
Co: ≤5 mg/kg
Cr: ≤5 mg/kg
Cu: ≤5 mg/kg
Fe: ≤10 mg/kg
Hg+: ≤4000 mg/kg
K: ≤50 mg/kg
Mg: ≤5 mg/kg
Mn: ≤5 mg/kg
Na: ≤50 mg/kg
Ni: ≤5 mg/kg
Pb: ≤5 mg/kg
Zn: ≤5 mg/kg

SMILES字符串

CC(=O)O[Hg]OC(C)=O

InChI

1S/2C2H4O2.Hg/c2*1-2(3)4;/h2*1H3,(H,3,4);/q;;+2/p-2

InChI key

BRMYZIKAHFEUFJ-UHFFFAOYSA-L

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相关类别

一般描述

Mercury(II) acetate forms various addition compounds with olefins. Polarographic evaluation of these addition compounds has been proposed.[1] It participates in the synthesis of nitrate esters, acetate esters, alcohols and ethers.[2]

应用

Mercury(II) acetate may be used in the preparation of 2-benzylidene-3(2H)-benzofuran-3-ones (aurones).[3]

警示用语:

Danger

危险分类

Acute Tox. 1 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - STOT RE 2

储存分类代码

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable


历史批次信息供参考:

分析证书(COA)

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Polarography of olefin-mercury (II) acetate addition compounds.
Fleet B and Jee RD.
Journal of Electroanalytical Chemistry, 25(3), 397-408 (1970)
Mercury-assisted solvolyses of alkyl halides: Simple procedures for the preparation of nitrate esters, acetate esters, alcohols and ethers.
McKillop A and Ford ME.
Tetrahedron, 30(15), 2467-2475 (1974)
Synthesis of 2-benzylidene-3 (2H)-benzofuran-3-ones (aurones) by oxidation of 2'-hydroxychalcones with mercury (II) acetate.
Sekizaki H.
Bulletin of the Chemical Society of Japan, 61(4), 1407-1409 (1988)
M E Ariza et al.
Environmental and molecular mutagenesis, 27(1), 30-33 (1996-01-01)
Little is known at the molecular level concerning the genotoxic effects following the acute exposure of eukaryotic cells to low concentrations of lead (II) or mercury (II). There have been conflicting reports concerning the mutagenic potential of these heavy metals
Erzsebet Farkas et al.
Toxicology in vitro : an international journal published in association with BIBRA, 24(1), 267-275 (2009-09-03)
Time lapse video photography was used to follow the movement of individual cells after in vitro treatment with Hg(II) acetate. Cellular changes of mercuric ions were characterized by their properties of causing reduced cellular mobility (10-50microM), and complete lack of

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