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Merck

650536

Sigma-Aldrich

庚烷

greener alternative

HPLC Plus, for HPLC, GC, and residue analysis, 99%

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1 L
$413.00

$413.00


预计发货时间2025年4月14日详情


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1 L
$413.00

About This Item

线性分子式:
CH3(CH2)5CH3
CAS号:
分子量:
100.20
Beilstein:
1730763
EC 号:
MDL编号:
UNSPSC代码:
12190000
PubChem化学物质编号:
NACRES:
NA.06

$413.00


预计发货时间2025年4月14日详情


获取大包装报价

等级

HPLC Plus

质量水平

蒸汽密度

3.5 (vs air)

蒸汽压

40 mmHg ( 20 °C)
83 mmHg ( 37.7 °C)

方案

≥98.5% (GC)
99%

表单

liquid

自燃温度

433 °F

expl. lim.

7 %

环保替代产品特性

Safer Solvents and Auxiliaries
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

技术

HPLC: suitable
gas chromatography (GC): suitable

杂质

≤0.0001% non-volatiles
≤0.01% water (Karl Fischer)
≤1.0 ppb Fluorescence (quinine) at 365 nm

卤代烷残留物

≤2 μg/L (as heptachlor epoxide)

折射率

n20/D 1.3850-1.3890
n20/D 1.387 (lit.)

沸点

98 °C (lit.)

mp

−91 °C (lit.)

溶解性

acetone: miscible(lit.)
carbon tetrachloride: soluble(lit.)
ethanol: very soluble(lit.)
water: insoluble(lit.)

密度

0.684 g/mL at 25 °C (lit.)

λ

H2O reference

紫外吸收

λ: 200 nm Amax: ≤1.0
λ: 225 nm Amax: ≤0.10
λ: 250 nm Amax: ≤0.01
λ: 300-400 nm Amax: ≤0.005

适用性

corresponds for IR spectroscopy
suitable for residue analysis

应用

food and beverages

环保替代产品分类

SMILES字符串

CCCCCCC

InChI

1S/C7H16/c1-3-5-7-6-4-2/h3-7H2,1-2H3

InChI key

IMNFDUFMRHMDMM-UHFFFAOYSA-N

正在寻找类似产品? 访问 产品对比指南

一般描述

我们致力于为您带来更加绿色的替代产品,这些产品遵守一项或多项绿色化学12项原则。作为一种更绿色溶剂,庚烷是己烷的环保替代品,可应用于HPLC和GC,成为“更安全的溶剂和助剂”。点击此处以获取更多信息。

庚烷(n-Heptane)是内燃机燃料中辛烷等级评定的主要参考燃料(PRF)。据报道,其十六烷值为56。其在流动反应器、激波管和快速压缩机中氧化的机制和动力学研究已被报道。[1]研究了其在不同温度和压力条件下的热分解。[2]研究了在氧化镁负载型钒催化剂存在下的氧化脱氢反应。[3]据报道,n-庚烷的Hβ沸石(MoP/Hβ)催化加氢异构化上负载的磷化钼通过掺杂再生金属而得到增强(Cr、Ni或Ce)。[4]

应用

HPLC 中更环保的己烷替代品。
分光光度法。
环境测试。
可使用庚烷( n -庚烷):
  • 制备薄层色谱法 (TLC) 分离纯化脂肪酸甲酯 N -酰基吡咯烷衍生物的混合溶剂。[5]
  • 通过全细胞双重氧化生成手性醇和庚酮。[6]
  • 以二氧化硅固定化脂肪酶催化乙酸与异丙醇的酯化反应,作为合成乙酸异丙酯的溶剂。[7]

特点和优势

更环保的己烷替代品

包装

M-Bottle for Solvents
As a global leader in lab reagents, we are constantly looking for new ways to optimize the safety of our products. The newly developed 4L solvent bottle design features advanced sealing technology that eliminates leaks to make the handling of solvents safer and more convenient than ever before.
See all the new features here!

其他说明

Pure-Pac ® II 容器需要用于分配溶剂的 Micromatic MacroValve 耦合器,Z560723。
农药残留分析(以七氯环氧化物计)<2 μg/L

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法律信息

Pure-Pac is a registered trademark of Merck KGaA, Darmstadt, Germany

警示用语:

Danger

危险分类

Aquatic Acute 1 - Aquatic Chronic 1 - Asp. Tox. 1 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Central nervous system

储存分类代码

3 - Flammable liquids

WGK

WGK 2

闪点(°F)

24.8 °F - closed cup

闪点(°C)

-4 °C - closed cup


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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High pressure pyrolysis of n-heptane.
Chakraborty JP and Kunzru D.
Journal of Analytical and Applied Pyrolysis, 86(1), 44-52 (2009)
Hydroisomerization of n-heptane over MoP/Hβ catalyst doped with metal additive.
Liu P, et al.
Fuel Processing Technology, 131, 311-316 (2015)
Activation of n-Heptane: A Study with VMgO Catalysts.
Dasireddy VDBC, et al.
Catalysis Letters, 144(4), 590-597 (2014)
Whole-cell double oxidation of n-heptane.
Muller CA, et al.
Journal of Biotechnology, 191, 196-204 (2014)
Madan Lal Verma et al.
Enzyme research, 2011, 919386-919386 (2011-05-24)
Selective production of fragrance fatty acid ester from isopropanol and acetic acid has been achieved using silica-immobilized lipase of Bacillus cereus MTCC 8372. A purified thermoalkalophilic extracellular lipase was immobilized by adsorption onto the silica. The effects of various parameters

商品

Development and validation of a fatty acid methyl esterification method, using methanolic HCl reagent, for FAME analysis by GC of vegetable oils and fats.

相关内容

Why should you have to choose between solvents that are ecological and those that are reliable? Enjoy both at once with our biorenewable and greener solutions. Cyrene™ solvent is a new dipolar aprotic alternative to common REACH restricted solvents, such as N methyl-2-pyrrolidone (NMP) and Dimethylformamide (DMF).

Questions

1–2 of 2 Questions  
  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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