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100 G
$251.00
500 G
$902.00
About This Item
线性分子式:
LiClO4
CAS号:
分子量:
106.39
EC 号:
MDL编号:
UNSPSC代码:
12352302
PubChem化学物质编号:
NACRES:
NA.21
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等级
purum p.a.
方案
≥98.0% (calc. based on dry substance, T)
表单
powder
反应适用性
reagent type: oxidant
杂质
≤3% water
pH值（酸碱度）
6.0-9.5 (25 °C, 106.4 g/L)
mp
236 °C (lit.)
溶解性
alcohol: soluble(lit.)
water: soluble(lit.)
痕量阴离子
chloride (Cl-): ≤50 mg/kg
sulfate (SO42-): ≤200 mg/kg
痕量阳离子
Ca: ≤100 mg/kg
Cd: ≤50 mg/kg
Co: ≤50 mg/kg
Cu: ≤50 mg/kg
Fe: ≤50 mg/kg
K: ≤500 mg/kg
Na: ≤100 mg/kg
Ni: ≤50 mg/kg
Pb: ≤50 mg/kg
Zn: ≤50 mg/kg
SMILES字符串
[Li+].[O-]Cl(=O)(=O)=O
InChI
1S/ClHO4.Li/c2-1(3,4)5;/h(H,2,3,4,5);/q;+1/p-1
InChI key
MHCFAGZWMAWTNR-UHFFFAOYSA-M
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一般描述
Lithium perchlorate (LiClO4) is a colorless lithium salt. Upon crystallization from its aqueous solution, it affords lithium perchlorate trihydrate (LiClO4.3H2O). It can be synthesized by reacting lithium chloride with perchloric acid.[1]
警示用语：
Danger
危险分类
Acute Tox. 4 Oral - Eye Dam. 1 - Ox. Sol. 2 - Skin Corr. 1A - STOT SE 3
靶器官
Respiratory system
储存分类代码
5.1A - Strongly oxidizing hazardous materials
WGK
WGK 1
闪点(°F)
Not applicable
闪点(°C)
Not applicable
Lithium perchlorate-accelerated Baylis-Hillman reactions.
Kawamura M and Kobayashi S.
Tetrahedron Letters, 40(8), 1539-1542 (1999)
Lithium perchlorate catalyzed reactions of indoles: An expeditious synthesis of bis (indolyl) methanes.
Yadav JS, et al.
Synthesis, 2001(5), 0783-0787 (2001)
Witold Darlewski et al.
Journal of hazardous materials, 175(1-3), 460-467 (2009-11-17)
A process of dibutyl sulphide (DBS) electro-oxidation using electrolysis and cyclic voltamperometry was investigated in water-methanol solution using different electrodes (platinum, boron doped diamond, graphite and glassy carbon). Obtained results indicate that the DBS electro-oxidation process is irreversible in voltamperometric
Francisco Palacios et al.
The Journal of organic chemistry, 67(7), 2131-2135 (2002-04-02)
Functionalized keto-enamines 6 were obtained by nucleophilic addition of enol ethers to the imine moiety of 2-azadienes derived from dehydroaspartic esters 4. Reactions of 2-azadiene 4c containing three electron-withdrawing substituents (CO(2)R) with enol ethers 5 in the presence of lithium
Shokaku Kim et al.
Organic letters, 4(21), 3735-3737 (2002-10-12)
[reaction: see text] N-Acyliminium cation of prolines was efficiently generated to accumulate in an undivided cell at 0 degrees C by an anodic oxidation of N-acylprolines or alpha'-phenylsulfanylated N-acylproline derivatives in a lithium perchlorate/nitromethane solution. The iminium cation intermediates gave
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