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Merck

383074

Sigma-Aldrich

硝酸铋(III) 五水合物

ACS reagent, ≥98.0%

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预计发货时间2025年4月21日详情


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100 G
$128.00
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About This Item

线性分子式:
Bi(NO3)3 · 5H2O
CAS号:
分子量:
485.07
EC 号:
UNSPSC代码:
12352302
PubChem化学物质编号:
NACRES:
NB.24

$128.00


预计发货时间2025年4月21日详情


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等级

ACS reagent

方案

≥98.0%

表单

(Powder or Crystals or Solid or Chunks)

反应适用性

reagent type: catalyst
core: bismuth

杂质

≤0.005% insolubles

沸点

75-80 °C (lit.)

mp

30 °C (lit.)

痕量阴离子

chloride (Cl-): ≤0.001%
sulfate (SO42-): ≤0.005%

痕量阳离子

Ag: ≤0.001%
As: ≤0.001%
Ca: ≤0.005%
Cu: ≤0.002%
Fe: ≤0.001%
K: ≤0.01%
Na: ≤0.02%
Pb: ≤0.002%

SMILES字符串

O=[N+](O[Bi](O[N+]([O-])=O)O[N+]([O-])=O)[O-].C

InChI

1S/CH4.Bi.3NO3/c;;3*2-1(3)4/h1H4;;;;/q;+3;3*-1

InChI key

DPLOIMSBRDLLRI-UHFFFAOYSA-N

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一般描述

硝酸铋 (Ⅲ) 五水合物是一种无毒、价廉、易操作且对空气不敏感的试剂,常用于有机合成中,具有广泛的应用前景。[1]

应用

硝酸铋 (III) 五水合物可用于以下工艺:
  • 硫代酰胺和硫脲类化合物转化成它们的氧衍生物。[2]
  • 在微波和无溶剂条件下芳香醛转化为羧酸。[3]
  • 在无溶剂条件下通过Pechmann缩合合成香豆素。[1]
  • 作为纯镧改性铋铁氧体(BFO)陶瓷合成的前体。[4]
  • 微波辐射下合成甲基硝基-2,4,6-三硝基苯的硝化剂。[5]
  • 作为制备 4-氨基-5-嘧啶腈和嘧啶酮衍生物的催化剂。[6]
  • 通过未保护的糖的Fischer糖基化合成糖苷。[7]
  • 氧化铋(Bi2O3)纳米粒子的合成。[8]
  • 4-替代 Hantzsch 1,4-二氢吡啶的氧化。[9]
  • 硫醚选择氧化成亚砜。[10]

象形图

Flame over circleCorrosion

警示用语:

Danger

危险声明

危险分类

Eye Dam. 1 - Ox. Sol. 2

储存分类代码

5.1B - Oxidizing hazardous materials

WGK

WGK 2

闪点(°F)

Not applicable

闪点(°C)

Not applicable


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Preparation of lead-free nanoglass frit powder for crystalline silicon solar cells.
Che Q, et al.
Applied Energy, 112, 657-662 (2013)
Bismuth (III) nitrate pentahydrate: a stoichiometric reagent for microwave induced mild and highly efficient aerial oxidation of aromatic aldehydes under solvent-free conditions.
Mukhopadhyay C and Datta A.
Catalysis Communications, 9(15), 2588-2592 (2008)
Bismuth Nitrate Pentahydrate: A Convenient Reagent for the Oxidation of Hantzsch 1,4-Dihydropyridines.
Mashraqui SH and Karnik MA.
Synthesis, 1998(5), 713-714 (1998)
Facile synthesis of bismuth oxide nanoparticles by a hydrolysis solvothermal route and their visible light photocatalytic activity.
Luan X, et al.
Environmental Engineering and Management Journal, 14(3), 703-707 (2015)
Bismuth (III) nitrate pentahydrate: a convenient and selective reagent for conversion of thiocarbonyls to their carbonyl compounds.
Mohammadpoor-Baltork I, et al.
Tetrahedron Letters, 44(3), 591-594 (2003)

Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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