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Merck

210056

Sigma-Aldrich

高碘酸钾

99.8%, ACS reagent

别名:

过碘酸钾, 高碘酸 钾盐

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预计发货时间2025年4月21日详情


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100 G
$407.00
500 G
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About This Item

线性分子式:
KIO4
CAS号:
分子量:
230.00
EC 号:
MDL编号:
UNSPSC代码:
12352300
PubChem化学物质编号:
NACRES:
NA.21

$407.00


预计发货时间2025年4月21日详情


获取大包装报价

等级

ACS reagent

方案

99.8%
99.8-100.3% (ACS specification)

表单

powder

反应适用性

reagent type: oxidant

杂质

≤0.01% other halogens

pH值(酸碱度)

~5.1 (25 °C, 5 g/L)

mp

582 °C (lit.)

痕量阳离子

Mn: ≤1 ppm

SMILES字符串

[K+].[O-]I(=O)(=O)=O

InChI

1S/HIO4.K/c2-1(3,4)5;/h(H,2,3,4,5);/q;+1/p-1

InChI key

FJVZDOGVDJCCCR-UHFFFAOYSA-M

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一般描述

高碘酸钾被广泛用作氧化剂。[1]在碱性介质中通过非光化学途径产生单线态氧 ( 1 O 2 )。这种单线态氧可以选择性地氧化水性有机污染物。[2]

应用

高碘酸钾可用作显色剂,用于吩噻嗪药物的敏感估计(纯形式或药物制剂)。[3]也可用于以下情况:
  • 制备用于钌表面抛光的硅基浆料。[4]
  • 制备用于钌和铜抛光的含甘氨酸浆料。[5]
  • 土壤和肥料样品中锰的分光光度法测定。4

警示用语:

Danger

危险分类

Aquatic Acute 1 - Eye Dam. 1 - Ox. Sol. 1 - Skin Corr. 1C - STOT RE 1

靶器官

Thyroid

储存分类代码

5.1A - Strongly oxidizing hazardous materials

WGK

WGK 3


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Alok D Bokare et al.
Environmental science & technology, 49(24), 14392-14400 (2015-11-26)
A nonphotochemical generation of singlet oxygen ((1)O2) using potassium periodate (KIO4) in alkaline condition (pH > 8) was investigated for selective oxidation of aqueous organic pollutants. The generation of (1)O2 was initiated by the spontaneous reaction between IO4(-) and hydroxyl
Determination of some phenothiazine drugs based on colour reaction with potassium periodate.
Basavaiah K, et al.
Analytical Letters, 33(1), 43-51 (2000)
Milne GWA.
Gardner's Commercially Important Chemicals: Synonyms, Trade Names, and Properties, 513-513 (2005)
Improved removal selectivity of ruthenium and copper by glycine in potassium periodate (KIO4)-based slurry.
Zeng X, et al.
Journal of the Electrochemical Society, 159(11), C525-C529 (2012)
Ruthenium polishing using potassium periodate as the oxidizer and silica abrasives.
Peethala BC and Babu SV.
Journal of the Electrochemical Society, 158(3), H271-H276 (2011)

Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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