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Merck

185302

Sigma-Aldrich

二异丙基醚

ReagentPlus®, 99%, contains either BHT or hydroquinone as stabilizer

别名:

异丙醚

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$136.00
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1 L
$136.00
2.5 L
$206.00

About This Item

线性分子式:
(CH3)2CHOCH(CH3)2
CAS号:
分子量:
102.17
Beilstein:
1731256
EC 号:
MDL编号:
UNSPSC代码:
12191502
PubChem化学物质编号:
NACRES:
NA.07

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等级

reagent

质量水平

蒸汽密度

3.5 (vs air)

蒸汽压

120 mmHg ( 20 °C)

产品线

ReagentPlus®

方案

99%

表单

liquid

自燃温度

827 °F

expl. lim.

1-21 %, 100 °F

dilution

(for general lab use)

折射率

n20/D 1.367 (lit.)

沸点

68-69 °C (lit.)

mp

−85 °C (lit.)

密度

0.725 g/mL at 25 °C (lit.)

SMILES字符串

CC(C)OC(C)C

InChI

1S/C6H14O/c1-5(2)7-6(3)4/h5-6H,1-4H3

InChI key

ZAFNJMIOTHYJRJ-UHFFFAOYSA-N

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一般描述

Diisopropyl ether is a colorless liquid. It is widely used as a solvent for the isolation of fats and oils. It can be synthesized from isopropyl alcohol. Its mixture with isooctane has been added to the gasoline fuel as an antiknocking agent.[1] Its synthesis from propylene and water in a single-pass trickle-bed reactor in the presence of an ion-exchange resin catalyst Amberlyst 15 has been proposed.[2] Its efficacy as a fuel additive has been reported. When released in the atmosphere, it undergoes photodecomposition by reacting with OH radicals. Kinetics and mechanism of its reaction in atmosphere have been reported.[3]

应用

Diisopropyl ether may be employed as a solvent for the preparation of aliphatic and aromatic cyanohydrins.[4]

法律信息

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

象形图

FlameExclamation mark

警示用语:

Danger

危险声明

危险分类

Flam. Liq. 2 - STOT SE 3

靶器官

Central nervous system

补充剂危害

储存分类代码

3 - Flammable liquids

WGK

WGK 1

闪点(°F)

-20.2 °F - closed cup

闪点(°C)

-29 °C - closed cup


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Atmospheric chemistry of automotive fuel additives: diisopropyl ether.
Wallington TJ, et al.
Environmental Science & Technology, 27(1), 98-104 (1993)
Single stage synthesis of diisopropyl ether-an alternative octane enhancer for lead-free petrol.
Heese FP, et al.
Catalysis Today, 49(1), 327-335 (1999)
Eagleson M.
Concise Encyclopedia Chemistry, 325-325 (1994)
Novel (R)-oxynitrilase sources for the synthesis of (R)-cyanohydrins in diisopropyl ether.
Kiljunen E and Kanerva LT.
Tetrahedron Asymmetry, 8(8), 1225-1234 (1997)
P Adlercreutz
Biochimica et biophysica acta, 1163(2), 144-148 (1993-05-13)
Horse liver alcohol dehydrogenase and alpha-chymotrypsin were deposited on a porous support material, Celite. After equilibration at a well-defined water activity, the catalytic activity was measured with diisopropyl ether as reaction medium. The effects of the presence of polyols and

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