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描述
Organic Salt
品質等級
形狀
solid
成份
14-16 wt% loading of base
反應適用性
core: lithium
SMILES 字串
[Li]N([Si](C)(C)C)[Si](C)(C)C
InChI
1S/C6H18NSi2.Li/c1-8(2,3)7-9(4,5)6;/h1-6H3;/q-1;+1
InChI 密鑰
YNESATAKKCNGOF-UHFFFAOYSA-N
一般說明
Lithium bis(trimethylsilyl)amide is a non-nucleophilic strong Brønsted base, which is generally soluble in most of the nonpolar organic solvents. It is most commonly employed in organic reactions.
應用
Base employed in generating enolates for the preparation of lactone precursors, pyranones, and cyclohexanes. Used to catalyze the addition of phosphine P-H bonds to carbodiimides leading to phosphaguanidines.[6] Also used in a novel three-step synthesis of disubstituted 1,2,5-thiadiazoles. For general uses, product is also available in powdered form (324620)
特點和優勢
ChemBeads are chemical coated glass beads. ChemBeads offer improved flowability and chemical uniformity perfect for automated solid dispensing and high-throughput experimentation. The method of creating ChemBeads uses no other chemicals or surfactants allowing the user to accurately dispense sub-milligram amounts of chemical.
其他說明
- High-Throughput Reaction Screening with Nanomoles of Solid Reagents Coated on Glass Beads
- Versatile Methods to Dispense Sub-Milligram Quantities of Solids using Chemical Coated Beads for High-Throughout Experimentation
- ChemBead Enabled High-Throughput Cross-Electrophile Coupling Reveals a New Complementary Ligand
訊號詞
Danger
危險聲明
危險分類
Eye Dam. 1 - Flam. Sol. 1 - Self-heat. 1 - Skin Corr. 1B
安全危害
儲存類別代碼
4.2 - Pyrophoric and self-heating hazardous materials
水污染物質分類（WGK）
WGK 3
閃點（°F）
62.6 °F - closed cup
閃點（°C）
17 °C - closed cup
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分析证书(COA)
Lot/Batch Number
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If you require a particular version, you can look up a specific certificate by the Lot or Batch number.
ChemBead Enabled High-Throughput Cross-Electrophile Coupling Reveals a New Complementary Ligand
Aguirre A L, et al.
Chemistry (Weinheim An Der Bergstrasse, Germany), 27(51), 12981-12986 (2021)
Structural Studies of Cesium, Lithium/Cesium, and Sodium/Cesium Bis(trimethylsilyl)amide (HMDS) Complexes
Ojeda-Amador A I, et al.
Inorganic Chemistry, 55(11), 5719-5728 (2016)
Alkali-metal-catalyzed addition of primary and secondary phosphines to carbodiimides. A general and efficient route to substituted phosphaguanidines
Zhang W X, et al.
Chemical Communications (Cambridge, England), 3812-4, 36-36 (2006)
High-Throughput Reaction Screening with Nanomoles of Solid Reagents Coated on Glass Beads
Tu N P, et al.
Angewandte Chemie (International Edition in English), 58(24), 7987-7991 (2019)
Tatsuya Nitabaru et al.
Journal of the American Chemical Society, 131(38), 13860-13869 (2009-09-10)
Full details of an anti-selective catalytic asymmetric nitroaldol reaction promoted by a heterobimetallic catalyst comprised of Nd(5)O(O(i)Pr)(13), an amide-based ligand, and NaHMDS (sodium hexamethyldisilazide) are described. A systematic synthesis and evaluation of amide-based ligands led to the identification of optimum
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