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Merck

939013

Copper(I) iodide ChemBeads

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别名:

Cuprous iodide

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About This Item

经验公式(希尔记法):
CuI
CAS号:
分子量:
190.45
分類程式碼代碼:
12352100

描述

Inorganic Salt

品質等級

形狀

solid

成份

loading of base, 14-16 wt. %

反應適用性

reagent type: catalyst
core: copper
reaction type: click chemistry

SMILES 字串

[Cu+].[I-]

InChI

1S/Cu.HI/h;1H/q+1;/p-1

InChI 密鑰

LSXDOTMGLUJQCM-UHFFFAOYSA-M

一般說明

Copper(I) iodide ChemBeads are the inorganic Copper(I) iodide salt coated on glass beads.

應用

Copper Iodide has many applications in organic reactions, including living radical polymerizations (Atom Transfer Radical Polymerization or ATRP) and cross coupling reactions. CuI has also been used in the fabrication of solar cells, photoluminescents, and nanocrystal synthesis.
Optimal catalyst for stereospecific and regioselective reaction of silacyclopropanes with carbonyl compounds.
For general uses, product is also available in powdered form 205540

特點和優勢

ChemBeads are chemical coated glass beads. ChemBeads offer improved flowability and chemical uniformity perfect for automated solid dispensing and high-throughput experimentation. The method of creating ChemBeads uses no other chemicals or surfactants allowing the user to accurately dispense sub-milligram amounts of chemical.

訊號詞

Danger

危險分類

Aquatic Chronic 2 - Eye Dam. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT RE 1 Oral

標靶器官

Thyroid

儲存類別代碼

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable


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Ana L Aguirre et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 27(51), 12981-12986 (2021-07-08)
High-throughput experimentation (HTE) methods are central to modern medicinal chemistry. While many HTE approaches to C-N and Csp2 -Csp2 bonds are available, options for Csp2 -Csp3 bonds are limited. We report here how the adaptation of nickel-catalyzed cross-electrophile coupling of
Noah P Tu et al.
Angewandte Chemie (International ed. in English), 58(24), 7987-7991 (2019-03-21)
Technologies that enable rapid screening of diverse reaction conditions are of critical importance to methodology development and reaction optimization, especially when molecules of high complexity and scarcity are involved. The lack of a general solid dispensing method for chemical reagents

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