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Merck

90781

Sigma-Aldrich

三丁胺

puriss. plus, ≥99.5% (GC)

别名:

Tri-n-butylamine

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10 ML
$119.00
50 ML
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About This Item

线性分子式:
[CH3(CH2)3]3N
CAS号:
分子量:
185.35
Beilstein:
1698872
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.21

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蒸汽密度

6.38 (vs air)

质量水平

蒸汽压

0.3 mmHg ( 20 °C)
2.4 mmHg ( 55 °C)

等级

puriss. plus

方案

≥99.5% (GC)

表单

liquid

自燃温度

410 °F

expl. lim.

6 %

技术

GC/GC: suitable

杂质

≤0.2% water

折射率

n20/D 1.428 (lit.)
n20/D 1.429

沸点

216 °C (lit.)

mp

−70 °C (lit.)

密度

0.778 g/mL at 25 °C (lit.)

官能团

amine

SMILES字符串

CCCCN(CCCC)CCCC

InChI

1S/C12H27N/c1-4-7-10-13(11-8-5-2)12-9-6-3/h4-12H2,1-3H3

InChI key

IMFACGCPASFAPR-UHFFFAOYSA-N

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一般描述

三丁胺是一种叔胺。据报道,它可以防止低碳钢在HCl溶液中被腐蚀。[1]

应用

三丁胺(n-Bu3N)可用于以下研究:
  • 组成液相色谱串联质谱(LC-MS / MS)的流动相。[2]
  • 制备PdCl,N和PdOAc,N (钯纳米颗粒)。[3]
  • 作为3-溴噻吩并[3,2-c]吡啶-4-(5H)-酮合成过程的添加剂。[4]

象形图

Skull and crossbones

警示用语:

Danger

危险分类

Acute Tox. 1 Inhalation - Acute Tox. 2 Dermal - Acute Tox. 4 Oral - Skin Irrit. 2

储存分类代码

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 1

闪点(°F)

145.4 °F - closed cup

闪点(°C)

63 °C - closed cup

个人防护装备

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Palladium nanoparticles obtained from palladium salts and tributylamine in molten tetrabutylammonium bromide: their use for hydrogenolysis-free hydrogenation of olefins.
Le Bras J, et al.
New. J. Chem., 28(12), 1550-1553 (2004)
Alexander S Misharin et al.
Analytical chemistry, 77(2), 459-470 (2005-01-15)
The analytical performance of an atmospheric pressure sampling, multiple-channel, high-throughput mass spectrometer was investigated using samples of a variety of types. The instrument, based on an array of cylindrical ion traps, was built with four independent channels and here is
I E Flesch et al.
Infection and immunity, 56(6), 1464-1469 (1988-06-01)
Bone marrow-derived murine macrophages are able to inhibit the growth of Mycobacterium bovis and of some strains of M. tuberculosis after stimulation with either recombinant gamma interferon (rIFN-gamma) or lymphokines from antigen-specific T-cell clones. To elucidate the mechanism(s) involved in
A Helenius et al.
The Journal of general virology, 58 Pt 1, 47-61 (1982-01-01)
The effect of five lysosomotropic weak bases (chloroquine, amantadine, tributylamine, methylamine and NH4C1) on Semliki Forest virus (SFV) infection has been studied in BHK-21 cells. When present at concentrations equal to or greater than 0.1, 0.5, 2, 15 and 15
Christopher J Jones et al.
Journal of chromatography. A, 1217(4), 479-488 (2009-12-17)
Reverse-phase ion-pair high performance liquid chromatography (RPIP-HPLC) and ultra-performance liquid chromatography (RPIP-UPLC) are increasingly popular chromatographic techniques for the separation of organic compounds. However, the fine details of the RPIP separation mechanism are still being debated. Many factors including type

Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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