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Merck

81942

Sigma-Aldrich

丙酸酐

purum, ≥96.0% (NT)

别名:

初油酸酐

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About This Item

线性分子式:
(CH3CH2CO)2O
CAS号:
分子量:
130.14
Beilstein:
507066
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

蒸汽密度

4.5 (vs air)

品質等級

蒸汽壓力

10 mmHg ( 57.7 °C)

等級

purum

化驗

≥96.0% (NT)

形狀

liquid

自燃溫度

545 °F

expl. lim.

11.9 %

折射率

n20/D 1.404 (lit.)
n20/D 1.404

bp

167 °C (lit.)

mp

−43 °C (lit.)

溶解度

H2O: decomposes (when in contact with water)

密度

1.010 g/mL at 20 °C
1.015 g/mL at 25 °C (lit.)

SMILES 字串

CCC(=O)OC(=O)CC

InChI

1S/C6H10O3/c1-3-5(7)9-6(8)4-2/h3-4H2,1-2H3

InChI 密鑰

WYVAMUWZEOHJOQ-UHFFFAOYSA-N

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應用

Propionic anhydride can be used:
  • As an esterifying reagent in the modification of cassava starch by acylation reaction.
  • As a reactant along with anisole in the synthesis of 4-methoxypropiophenone using various solid acid catalysts via Friedel−Crafts acylation reaction.
  • As a reagent in the synthesis of cyanohydrin esters by treating KCN with aldehyde in presence of bimetallic titanium(salen) complex catalyst.

其他說明

可能实行销售限制

象形圖

Corrosion

訊號詞

Danger

危險聲明

危險分類

Eye Dam. 1 - Skin Corr. 1B

儲存類別代碼

8A - Combustible corrosive hazardous materials

水污染物質分類(WGK)

WGK 1

閃點(°F)

165.2 °F - closed cup

閃點(°C)

74 °C - closed cup

個人防護裝備

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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Slide 1 of 2

1 of 2

Modification of cassava starch by using propionic anhydride and properties of the starch-blended polyester polyurethane
Santayanon R and Wootthikanokkhan J
Carbohydrate Polymers, 51(1), 17-24 (2003)
Synthetic and mechanistic studies on asymmetric cyanohydrin synthesis using a titanium (salen) bimetallic catalyst
Belokon YN, et al.
Tetrahedron, 60(46), 10433-10447 (2004)
Robert Meatherall et al.
Journal of analytical toxicology, 33(8), 525-531 (2009-10-31)
Azide in human blood and plasma samples was derivatized with propionic anhydride in a headspace vial without prior sample preparation. The reaction proceeds quickly at room temperature to form propionyl azide. A portion of the headspace was assayed by gas
Surendra Nimesh et al.
International journal of pharmaceutics, 337(1-2), 265-274 (2007-01-27)
Polyethylenimine (750 kDa) has been derivatized to influence the proton sponge mechanism and hydrophobic-hydrophilic balance. The polymer was acylated using acid anhydrides of varying carbon chain length, followed by cross-linking with PEG-bis-P to form compact nanoparticles. The chemical linkages in
J G Guillot et al.
Journal of analytical toxicology, 21(2), 127-133 (1997-03-01)
We present an analytical method for the determination of heroin, free 6-acetylmorphine (6-AM), and free morphine in blood, urine, and vitreous humor. This method is used in postmortem cases where heroin is the suspected cause of death. The analytical protocol

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