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Merck

71950

Sigma-Aldrich

亚硒酸钠

anhydrous, ≥90.0% (RT)

别名:

Selenious acid disodium salt

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100 G
$145.00
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国内现货,预计发货时间2025年4月01日详情


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100 G
$145.00
500 G
$410.00

About This Item

线性分子式:
Na2SeO3
CAS号:
分子量:
172.94
EC 号:
MDL编号:
UNSPSC代码:
12352302
PubChem化学物质编号:
NACRES:
NA.22

$145.00


国内现货,预计发货时间2025年4月01日详情


获取大包装报价

等级

for analytical purposes

质量水平

方案

≥90.0% (RT)

表单

powder

缺失

≤0.5% loss on drying, 200 °C

mp

>350 °C (lit.)

SMILES字符串

[Na+].[Na+].[O-][Se]([O-])=O

InChI

1S/2Na.H2O3Se/c;;1-4(2)3/h;;(H2,1,2,3)/q2*+1;/p-2

InChI key

BVTBRVFYZUCAKH-UHFFFAOYSA-L

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应用

亚硒酸钠可用于:
  • 在加热和微波条件下使苯偶姻脱氢转化为苯偶酰, 黄烷酮转化为黄酮。[1]
  • 作为催化剂与半胱氨酸和谷胱甘肽一起参与邻--二溴化合物的还原脱溴转化为烯烃。[2]
  • 通过与氯化甲基汞和还原型谷胱甘肽或半胱氨酸反应制备双(甲汞)硒化物(BMS)。[3]

亚硒酸钠是合成硒化锌 (ZnSe) 过程中常见的硒来源。[4]其被作合成硒化铋纳米复合材料、[5] 镍钴硒化物、[6] 硒纳米带 [7] t -硒纳米管的关键前体。[8]

象形图

Skull and crossbonesEnvironment

警示用语:

Danger

危险分类

Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Chronic 2 - Eye Irrit. 2 - Skin Irrit. 2 - Skin Sens. 1

补充剂危害

储存分类代码

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 2

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Cellulose-directed growth of selenium nanobelts in solution.
Lu Q, et al.
Chemistry of Materials, 18(1) (2006)
Sodium selenite-dimethylsulfoxide: a highly efficient reagent for dehydrogenation
Lamba M and Makrandi JK
J. Chem. Res. (M), 2008(4), 225-226 (2008)
Nucleation- dissolution- recrystallization: a new growth mechanism for t-selenium Nanotubes.
Xi G, et al.
Crystal Growth & Design, 6(2), 577-582 (2006)
Hydrothermal synthesis and high photocatalytic activity of 3D wurtzite ZnSe hierarchical nanostructures.
Cao F, et al.
The Journal of Physical Chemistry C, 112(44), 17095-17101 (2008)
Selenium-catalysed debromination of vic-dibromides to alkenes with cysteine or glutathione
Yanada, Kazuo and Yanada, Reiko and Meguri, Haruo
Journal of the Chemical Society. Chemical Communications, 2008(10), 730-732 (1990)

商品

Antioxidants protect biological systems from oxidative damage produced by oxygen-containing free radicals and from redoxactive transition metal ions such as iron, copper, and cadmium.

抗氧化剂可保护生物系统免受含氧自由基和氧化还原过渡金属离子(如铁、铜和镉)引起的氧化损伤。

Questions

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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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